60464-75-7

Basic information

• Product Name: Trimethyl-[(S)-(7-oxa-bicyclo[4.1.0]hept-2-yl)oxy]-silane
• CAS NO: 60464-75-7
• Molecular Weight: 186.326
• Mol File: 60464-75-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Trimethyl-[(S)-(7-oxa-bicyclo[4.1.0]hept-2-yl)oxy]-silane(CAS DataBase Reference)
• NIST Chemistry Reference: Trimethyl-[(S)-(7-oxa-bicyclo[4.1.0]hept-2-yl)oxy]-silane(60464-75-7)
• EPA Substance Registry System: Trimethyl-[(S)-(7-oxa-bicyclo[4.1.0]hept-2-yl)oxy]-silane(60464-75-7)

Safety Data

• Hazardous Substances Data: 60464-75-7(Hazardous Substances Data)

Upstream product

• 92735-08-5 3-trimethylsiloxycyclohexene 
• 6426-26-2 (S)-cyclohex-2-en-1-ol 

Downstream Products

• 92838-29-4 (1R,2S,3R)-3-Isocyano-cyclohexane-1,2-diol 
• 92838-29-4 (1S,2S,3R)-3-Isocyano-cyclohexane-1,2-diol 
• 92735-09-6 (2R,3S)-2-decyl-3-hydroxycyclohexan-1-one 
• 72029-30-2 (2S,3S)-2,3-epoxy-cyclohexan-1-one 
• 92838-28-3 (1S,2R,3S)-1-Isocyano-2,3-bis-trimethylsilanyloxy-cyclohexane 
• 92838-28-3 (1S,2R,3R)-1-Isocyano-2,3-bis-trimethylsilanyloxy-cyclohexane 

Relevant articles and documents

Solvent Tuning of Diastereoselectivity in Dimethyldioxirane Epoxidation Reactions

Diastereoselectivity in the epoxidation of cyclohex-2-en-1-ol shows a remarkable solvent dependence.In some solvent systems the substrate OH group apparently can provide a cis selectivity through H-bonding.

Diastereoselectivity in the epoxidation of substituted cyclohexenes by dimethyldioxirane

Three series of compounds based on the cyclohexene framework have been epoxidized by dimetbyldioxirane. A pronounced dependence of epoxide diastereoselectivity on substituent has been observed. In addition there is a solvent influence on this stereoselectivity. The results have been explained by invoking steric, H-bonding, and dipole - dipole influences on the epoxide stereochemistry.