60622-52-8Relevant articles and documents
Reaction of allylic and benzylic alcohols and esters with PPh 3/I2: One-pot synthesis of β,γ-unsaturated compounds
Alvarez-Manzaneda,Chahboun,Cabrera Torres,Alvarez,Alvarez-Manzaneda,Haidour,Ramos López
, p. 3755 - 3759 (2005)
The treatment of tertiary and secondary allylic alcohols containing a terminal double bond, and their acetyl derivatives, with triphenylphosphine and iodine under mild conditions leads regiospecifically and in high stereoselectivity to the corresponding primary allylic iodides, which can react 'in situ' with diverse nucleophiles. Primary allylic alcohols and benzyl alcohols and acetates are also transformed into the corresponding iodides under these conditions.
Regioselective Preparation of Allylic Sulfones by Palladium-Catalyzed Reactions of Allylic Nitro Compounds with Sodium Benzenesulfinate
Ono, Noboru,Hamamoto, Isami,Kawai, Takashi,Kaji, Aritsune,Tamura, Rui,Kakihana, Masato
, p. 405 - 410 (2007/10/02)
Treatment of allylic nitro compounds with sodium benzenesulfinate in the presence of 5 molpercent of Pd(PPh3)4 in N,N-dimethylformamide (DMF) at 20-70 deg C for 1-10 h resulted in the formation of allylic sulfones with predominance of kinetically controll
REGIOSELECTIVE SYNTHESIS OF ALLYLIC SULFONES BY PALLADIUM-CATALYZED DENITRO-SULFONYLATION OF ALLYLIC NITRO COMPOUNDS
Tamura, Rui,Hayashi, Koji,Kakihana, Masato,Tsuji, Masanori,Oda, Daihei
, p. 851 - 854 (2007/10/02)
Allylic nitro compounds undergo denitro-sulfonylation catalyzed by Pd(PPh3)4 or Pd(PPh3)4+NaNO2 with PhSO2Na*2H2O to afford allylic sulfones regioselectively.