6065-04-9

Basic information

• Product Name: 3-NITRO-3-NONENE
• Synonyms: 3-NITRO-3-NONENE
• CAS NO: 6065-04-9
• Molecular Formula: C₉H₁₇NO₂
• Molecular Weight: 171.27
• Mol File: 6065-04-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 271.23°C (rough estimate)
• Flash Point: 92.1°C
• Appearance: /
• Density: 0.9644 (estimate)
• Vapor Pressure: 0.0407mmHg at 25°C
• Refractive Index: 1.4513 (estimate)
• CAS DataBase Reference: 3-NITRO-3-NONENE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-NITRO-3-NONENE(6065-04-9)
• EPA Substance Registry System: 3-NITRO-3-NONENE(6065-04-9)

Safety Data

• Hazardous Substances Data: 6065-04-9(Hazardous Substances Data)

Usage

Description

3-NITRO-3-NONENE is a nitroolefin compound that has been identified in the exhaust emissions from gasoline engines, contributing to urban air pollution.

Uses

Used in Environmental Studies:
3-NITRO-3-NONENE is used as an indicator for monitoring air quality in urban areas, as its presence is associated with automobile exhaust emissions. Understanding the levels of 3-NITRO-3-NONENE can help in assessing the impact of vehicular pollution and informing strategies for reducing air pollution and its associated health risks.

InChI:InChI=1/C9H17NO2/c1-3-5-6-7-8-9(4-2)10(11)12/h8H,3-7H2,1-2H3/b9-8-

Upstream product

• 344297-99-0 3-nitro-4-nonanol 
• 66-25-1 hexanal 
• 108-03-2 1-Nitropropane 
• 6329-58-4 Diethyl 1-nitropropanephosphonate 

Relevant articles and documents

Facile and highly stereoselective one-pot synthesis of either (E)- or (Z)-nitro alkenes

(Chemical Equation Presented) Aliphatic aldehydes were reacted with nitro alkanes in the presence of catalytic amounts of piperidine over 4 A molecular sieves. Simply by changing reaction conditions (solvent and temperature) it is possible to control the stereochemical outcome of the reactions, obtaining pure (E)- and (Z)-nitro alkenes in high to excellent yields. The role of molecular sieves on the stereochemical control seems crucial in addition to that of piperidine, especially for the synthesis of the Z isomer.

A modified Horner-Wadsworth-Emmons reaction for the synthesis of nitroalkenes

A range of trisubstituted nitroalkenes are available from the reaction of an α-nitrophosphonate anion and an aldehyde in tetrahydrofuran under reflux.