60733-10-0

Basic information

• Product Name: 2-Cyclohexen-1-ol, 3-methyl-, (1S)-
• CAS NO: 60733-10-0
• Molecular Formula: C7H12O
• Molecular Weight: 112.172
• Mol File: 60733-10-0.mol
• Article Data: 28

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-ol, 3-methyl-, (1S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-ol, 3-methyl-, (1S)-(60733-10-0)
• EPA Substance Registry System: 2-Cyclohexen-1-ol, 3-methyl-, (1S)-(60733-10-0)

Safety Data

• Hazardous Substances Data: 60733-10-0(Hazardous Substances Data)

Upstream product

• 1193-18-6 3-methylcyclohexen-2-one 
• 75411-49-3 3-methyl-2-cyclohexen-1-yl acetate 
• 21378-21-2 3-methylcyclohex-2-en-1-ol 
• 108-22-5 Isopropenyl acetate 
• 123-20-6 vinyl n-butyrate 
• 2146-71-6 vinyl laurate 
• 591-49-1 1-methylcyclohex-1-ene 
• 69744-92-9 Phthalic acid mono-((S)-3-iodo-cyclohex-2-enyl) ester 
• 56671-82-0 3-Iodocyclohex-2-enone 
• 51326-26-2 α-bromo-3-methylcyclohex-2-en-1-one 
• 220959-44-4 (S)-1-methyl-1-cyclohexen-3-yl benzoate 
• 1489-56-1 1-methyl-1,3-cyclohexadiene 
• 69744-94-1 (S)-(-)-iodocyclohex-2-en-1-ol 
• 917-54-4 methyllithium 

Downstream Products

• 69698-85-7 (3S,8S,9S,10R,13S,14S,17S)-3-Acetoxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthrene-17-carboxylic acid (S)-3-methyl-cyclohex-2-enyl ester 
• 50538-78-8 (1S,3S)-3-methylcyclohexanol 
• 439667-21-7 (1S,2S,3S)-1-methylcyclohexane-1,2,3-triol 
• 275825-03-1 (S)-6-methyl-6-(4-methylpent-4-en-1-yl)-1-vinylcyclohex-1-ene 
• 275825-05-3 (S)-2-methyl-2-(4-methylpent-4-en-1-yl)cyclohexanone 
• 275825-12-2 C₁₅H₂₆O 
• 1344731-15-2 (2S)-2-methyl-2-(4-methylpent-4-en-1-yl)cyclohexanol 
• 1344731-01-6 2-methyl-5-((S)-1-methylcyclohex-2-en-1-yl)pent-1-en-3-yl acetate 
• 1344731-00-5 5-(1-methylcyclohex-2-en-1-yl)pent-1-en-3-ol 
• 112775-81-2 (1S,2S,3R)-2,3-epoxy-3-methylcyclohexyl tosylate 
• 88494-89-7 (R)-(+)-1-methyl-2-cyclohexen-1-ol 

Relevant articles and documents

Regio- And Stereoselective Addition of HO/OOH to Allylic Alcohols

A range of allylic alcohols are shown to readily react with ethereal H2O2 in the presence of catalytic amounts of Na2MoO4-gly or MoO2(acac)2, affording the C═C trans hydroxylation-hydroperoxylation products in good yields with high regio- and stereoselect

CHIRAL METAL COMPLEX COMPOUNDS

The invention comprises novel chiral metal complex compounds of the formula (I) wherein M, PR2, R3 and R4 are outlined in the description, its stereoisomers, in the form as a neutral complex or a complex cation with a suitable counter ion. The chiral metal complex compounds can be used in asymmetric reactions, particularly in asymmetric reductions of ketones, imines or oximes.

Synthesis of chiral building blocks for oxygenated terpenoids through a simultaneous and stereocontrolled construction of contiguous quaternary stereocenters by an ireland-claisen rearrangement

Methods for highly stereocontrolled syntheses of chiral building blocks with a triad of contiguous stereocenters, including two quaternary ones, have been developed. Ireland-Claisen rearrangement of the (Z)-silyl ketene acetal generated stereoselectively