607403-64-5Relevant articles and documents
Highly stereoselective synthesis of a seven-membered carbasugar via triisobutylaluminium promoted Claisen rearrangement
Jia, Cai,Zhang, Yongmin,Zhang, Lihe
, p. 2195 - 2199 (2007/10/03)
2-Methylene-5-vinyl-tetrahydrofuran derivative 6 was obtained from α-D-glucose. Treatment of 6 with triisobutylaluminium (TIBAL) induced Claisen expansion reaction to give the seven-membered carbasugar derivative 7, which represents a new type of chiral b