60753-94-8

Basic information

• Product Name: 1-ALLYL-1-METHOXY-CYCLOHEXANE
• Synonyms: 1-ALLYL-1-METHOXY-CYCLOHEXANE
• CAS NO: 60753-94-8
• Molecular Formula: C₁₀H₁₈O
• Molecular Weight: 154.24932
• Mol File: 60753-94-8.mol
• Article Data: 20

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-ALLYL-1-METHOXY-CYCLOHEXANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-ALLYL-1-METHOXY-CYCLOHEXANE(60753-94-8)
• EPA Substance Registry System: 1-ALLYL-1-METHOXY-CYCLOHEXANE(60753-94-8)

Safety Data

• Hazardous Substances Data: 60753-94-8(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 21, p. 71, 1980 DOI: 10.1016/S0040-4039(00)93627-X

Upstream product

• 933-40-4 cycloxexanone dimethyl ketal 
• 762-72-1 allyl-trimethyl-silane 
• 681-84-5 tetramethylorthosilicate 
• 108-94-1 cyclohexanone 
• 1825-61-2 Trimethylmethoxysilane 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 149-73-5 trimethyl orthoformate 
• 1123-34-8 1-allyl-1-cyclohexanol 
• 77-78-1 dimethyl sulfate 

Relevant articles and documents

Mesoporous aluminosilicate-catalyzed allylation of carbonyl compounds and acetals

A mesoporous aluminosilicate (Al-MCM-41) was found to be an effective heterogeneous catalyst for the reaction of both carbonyl compounds and acetals with allylsilanes to afford the corresponding homoallyl silyl ethers and homoallyl alkyl ethers, respectively. Both the mesoporous structure and the presence of aluminum moiety were indispensable for the high catalytic activity of Al-MCM-41. Moreover, Al-MCM-41 could catalyze the reaction of acetals chemoselectively in the presence of the corresponding carbonyl compounds. The solid acid catalyst Al-MCM-41 could be recovered easily by filtration and could be reused three times without a significant loss of catalytic activity.

Unusual carbon-carbon bond formations between allylboronates and acetals or ketals catalyzed by a peculiar indium(I) lewis acid

InIOTf has been uncovered as an effective Lewis acid catalyst for unprecedented nucleophilic substitution of acetals or ketals with allylboronates. A transmetalative SN1 mechanism is proposed in which a single InI center acts as a dual catalyst to activate both reagents sequentially. Contrary to the classic γ-selectivity of allylsilanes (Hosomi-Sakurai reaction), this InI-catalyzed borono variant displays distinct α-selectivity. Substrate scope and functional group tolerance proved to be excellent.

Iron(III) p-toluenesulfonate catalyzed synthesis of homoallyl ethers from acetals and aldehydes

Iron(III) p-toluenesulfonate, Fe(OTs)3·6H2O, is an inexpensive, versatile and commercially available catalyst for the allylation of acetals using allyltrimethylsilane to yield homoallyl ethers in moderate to good yields. The one-pot