60782-58-3

Basic information

• Product Name: TRIHEXYLSILANOL
• Synonyms: TRIHEXYLSILANOL
• CAS NO: 60782-58-3
• Molecular Formula: C18H40OSi
• Molecular Weight: 300.6
• Mol File: 60782-58-3.mol
• Article Data: 13

Chemical Properties

• Appearance: /
• CAS DataBase Reference: TRIHEXYLSILANOL(CAS DataBase Reference)
• NIST Chemistry Reference: TRIHEXYLSILANOL(60782-58-3)
• EPA Substance Registry System: TRIHEXYLSILANOL(60782-58-3)

Safety Data

• Hazardous Substances Data: 60782-58-3(Hazardous Substances Data)

Upstream product

• 3634-67-1 trihexylsilyl chloride 
• 2929-52-4 tri-n-hexylsilane 

Relevant articles and documents

Metal-free hydrogen evolution cross-coupling enabled by synergistic photoredox and polarity reversal catalysis

A synergistic combination of photoredox and polarity reversal catalysis enabled a hydrogen evolution cross-coupling of silanes with H2O, alcohols, phenols, and silanols, which afforded the corresponding silanols, monosilyl ethers, and disilyl ethers, respectively, in moderate to excellent yields. The dehydrogenative cross-coupling of Si-H and O-H proceeded smoothly with broad substrate scope and good functional group compatibility in the presence of only an organophotocatalyst 4-CzIPN and a thiol HAT catalyst, without the requirement of any metals, external oxidants and proton reductants, which is distinct from the previously reported photocatalytic hydrogen evolution cross-coupling reactions where a proton reduction cocatalyst such as a cobalt complex is generally required. Mechanistically, a silyl cation intermediate is generated to facilitate the cross-coupling reaction, which therefore represents an unprecedented approach for the generation of silyl cationviavisible-light photoredox catalysis.

COMPOSITION, PHOTOELECTRIC CONVERSION ELEMENT, AND IMAGING DEVICE

A composition contains a naphthalocyanine derivative represented by the following formula: where R1 to R8 are independently an alkyl group and R9 to R12 are independently an aryl group, and at least one hydrogen atom in at least one selected from the group consisting of R9, R10, R11, and R12 is substituted by an electron-withdrawing group.

COMPOSITION, NEAR-INFRARED PHOTOELECTRIC CONVERTER, AND IMAGING DEVICE

PROBLEM TO BE SOLVED: To provide a composition that exhibits high photoelectric conversion efficiency and has a property of high optical absorption in a near-infrared region. SOLUTION: A composition contains a naphthalocyanine derivative represented by the general formula (1) in the figure, where X is Si or C; R1 to R8 are each independently an alkyl group; and R9 to R14 are each independently an alkyl group, an alkoxy group, an aryl group, or a hydrogen atom. SELECTED DRAWING: None COPYRIGHT: (C)2019,JPOandINPIT