6102-32-5

Basic information

• Product Name: (4aS,8aS)-octahydronaphthalen-1(2H)-one
• Synonyms: (4aS,8aS)-octahydronaphthalen-1(2H)-one
• CAS NO: 6102-32-5
• Molecular Weight: 152.236
• Mol File: 6102-32-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4aS,8aS)-octahydronaphthalen-1(2H)-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4aS,8aS)-octahydronaphthalen-1(2H)-one(6102-32-5)
• EPA Substance Registry System: (4aS,8aS)-octahydronaphthalen-1(2H)-one(6102-32-5)

Safety Data

• Hazardous Substances Data: 6102-32-5(Hazardous Substances Data)

Upstream product

• 493-01-6 cis-decalin 

Relevant articles and documents

FUNCTIONALISATION OF SATURATED HYDROCARBONS. Part X. A COMPARATIVE STUDY OF CHEMICAL AND ELECTROCHEMICAL PROCESSES (GIF AND GIF-ORSAY SYSTEMS) IN PYRIDINE, IN ACETONE AND IN PYRIDINE-CO-SOLVENT MIXTURES

Six saturated hydrocarbons (cyclohexane, 3-ethylpentane, methylcyclopentane, cis- and trans-decalin and adamantane) were oxidised by the Gif system (iron catalyst, oxygen, zinc, carboxylic acid) and its electrochemical equivalent (Gif-Orsay system).Results obtained using various solvents (pyridine, acetone, pyridine-acetone mixtures) were similar for both systems.Total or partial replacement of pyridine with acetone affects the selectivity for secondary positions and lowers the ketone/secondary alcohol ratio.The formation of the same ratio of cis- and trans-decal-9-ol from both cis- and trans-decalin clearly demonstrates that tertiary alcohols result from a mechanism essentially radical in nature.