61142-86-7

Basic information

• Product Name: N-phenylcycloheptanamine
• Synonyms: N-phenylcycloheptanamine;N-phenylcycloheptamine
• CAS NO: 61142-86-7
• Molecular Formula: C₁₃H₁₉N
• Molecular Weight: 189.29666
• Mol File: 61142-86-7.mol
• Article Data: 19

Chemical Properties

• Boiling Point: 156 °C(Press: 11 Torr)
• Appearance: /
• Density: 1.000±0.06 g/cm3(Predicted)
• PKA: 5.46±0.20(Predicted)
• CAS DataBase Reference: N-phenylcycloheptanamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-phenylcycloheptanamine(61142-86-7)
• EPA Substance Registry System: N-phenylcycloheptanamine(61142-86-7)

Safety Data

• Hazardous Substances Data: 61142-86-7(Hazardous Substances Data)

Upstream product

• 79605-67-7 2-cycloheptenol 
• 62-53-3 aniline 
• 34564-56-2 cyclohepten-1-yl methyl ketone 
• 591-50-4 iodobenzene 
• 502-41-0 cycloheptanol 
• 108-86-1 bromobenzene 
• 5452-35-7 cycloheptanamine 
• 628-92-2 Cycloheptene 
• 291-64-5 cycloheptane 
• 98-95-3 nitrobenzene 
• 957-29-9 cycloheptyl 4-methylbenzenesulfonate 
• 502-42-1 cycloheptanone 
• 2404-35-5 cycloheptyl bromide 

Relevant articles and documents

Construction of α-Alkylated Amines by Iridium Complex-Catalyzed One-Step Transfer Hydrogenation of C=C and C=N Bonds

Hydrogenation of C=C bond and reductive amination are important transformations utilized in chemistry. An environmentally friendly, efficient, and facile one-pot transfer hydrogenation of C=C bond of enones and reductive amination of C=N bond of imines are reported using iridium complex as catalysts and formic acid as hydrogen source in aqueous medium. In this catalytic system, a wide range of α-alkylated amines were obtained in excellent yields by one-pot transfer hydrogenation of C=C bond and reductive amination. The practical application of this protocol is characterized by gram-scale transformation.

Band-Gap Narrowing of Highly Stable Heterogeneous ZrO2–ZnO Nanocomposites for the Reductive Amination of Carbonyl Compounds with Formic Acid and Triethylamine

The band gap of a material can be affected by factors such as size, doping materials, and oxygen vacancies. The decrease in band gap and change in state of ZrO2 with the addition of ZnO indicates interfacial interactions between ZrO2 and ZnO in the nanocomposites (NCs), which is further confirmed by the observed shift of the peaks in the Raman spectra. Heterobimetallic ZrO2–ZnO NCs were synthesized through a sustainable green approach by using sucrose isolated from Angelica gigas Nakai root extract. The highly stable NCs displayed excellent catalytic activity for reductive amination of carbonyl compounds utilizing HCO2H/(CH3CH2)3N as a hydrogen source. The high catalytic performance of the NCs was closely correlated with the narrow band gap and synergistic effect of ZrO2 with ZnO in the NCs.

Photoinduced Cross-Coupling of Amines with 1,2-Diiodobenzene and Its Application in the Synthesis of Carbazoles

A facile and efficient process for the preparation of various tertiary aminobenzenes and carbazole derivatives via photoinduced cross-coupling of amines with 1,2-diiodobenzene is reported. Mechanistic investigations indicate that the transformation proceeds via nucleo-philic addition of an amine to the benzyne intermediate accompanied with a proton transfer process, followed by an oxidative cyclization of the generated diphenylamine to furnish the corresponding carbazole products.