61166-04-9

Basic information

• Product Name: 9-Methyl-3-aminocarbazole
• Synonyms: 3-Amino-9-methyl-9H-carbazole;3-Amino-9-methylcarbazole;9-Methyl-3-aminocarbazole;9-Methylcarbazol-3-amine;9-methyl-9H-carbazol-3-amine
• CAS NO: 61166-04-9
• Molecular Formula: C₁₃H₁₂N₂
• Molecular Weight: 196.24778
• Mol File: 61166-04-9.mol
• Article Data: 13

Chemical Properties

• Melting Point: 174 °C
• Boiling Point: 415.4°Cat760mmHg
• Flash Point: 205°C
• Appearance: /
• Density: 1.2g/cm³
• Vapor Pressure: 4.13E-07mmHg at 25°C
• Refractive Index: 1.664
• PKA: 4.99±0.30(Predicted)
• CAS DataBase Reference: 9-Methyl-3-aminocarbazole(CAS DataBase Reference)
• NIST Chemistry Reference: 9-Methyl-3-aminocarbazole(61166-04-9)
• EPA Substance Registry System: 9-Methyl-3-aminocarbazole(61166-04-9)

Safety Data

• Hazardous Substances Data: 61166-04-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H12N2/c1-15-12-5-3-2-4-10(12)11-8-9(14)6-7-13(11)15/h2-8H,14H2,1H3

Upstream product

• 3077-85-8 3-Nitro-carbazol 
• 86-74-8 9H-carbazole 
• 1484-12-4 N-methylcarbazole 
• 17754-68-6 N,N'-dimethyl-N,N'-diphenyl-1,4-phenylenediamine 
• 61166-05-0 9-methyl-3-nitro-9H-carbazole 

Downstream Products

• 1353648-61-9 ethyl 4-(9-methyl-9H-carbazol-3-ylamino)-2-(4-nitrophenyl)-5-oxo-2,5-dihydro-3-furancarboxylate 
• 1234193-61-3 7-methyl-1,3-diphenyl-7H-pyrido[2,3-c]carbazole 

Relevant articles and documents

Carbazole-decorated fluorescent CdS quantum dots: A potential light-harvesting material

An organic-inorganic nanohybrid system (AMC-CdS QD) comprised of a fluorescent carbazole analog, AMC (3-amino-N-methyl carbazole), and CdS QDs has been synthesized, which shows promise as a sustainable energy harvesting material. FT-IR and 1H NMR spectroscopy have ascertained the covalent grafting of the carbazole moieties onto the mercaptopropionic acid (MPA)-capped surface of the CdS QDs. Detailed photophysical characterization of this nanohybrid system have confirmed the occurrence of efficient F?rster resonance energy transfer (FRET) from its organic to inorganic counterpart. This phenomenon was also demonstrated using SCC-DFTB-based quantum chemical calculations. As explored in the present work, the photoelectron transfer efficiency of AMC-CdS QDs signifies their plausible future applications as light-harvesting materials.

AMINATION AND HYDROXYLATION OF ARYLMETAL COMPOUNDS

In one aspect, the present disclosure provides methods of preparing a primary or secondary amine and hydroxylated aromatic compounds. In some embodiments, the aromatic compound may be unsubstituted, substituted, or contain one or more heteroatoms within the rings of the aromatic compound. The methods described herein may be carried out without the need for transition metal catalysts or harsh reaction conditions.

Non-deprotonative primary and secondary amination of (hetero)arylmetals

Herein we disclose a novel method for the facile transfer of primary (-NH2) and secondary amino groups (-NHR) to heteroaryl-as well as arylcuprates at low temperature without the need for precious metal catalysts, ligands, excess reagents, protecting and/or Erecting groups. This one-pot transformation allows unprecedented functional group tolerance and it is wellsuited for the amination of electron-rich, electron-deficient as well as structurally complex (hetero)arylmetals. In some of the cases, only catalytic amounts of a copper (l) salt is required.