6118-95-2Relevant articles and documents
A convenient one-pot synthesis of 1-aryl-substituted 4-iodopyrazol-3-ols via aromatisation and oxidative iodination reactions
Liu, Jingjing,Yang, Shanguang,Dong, Ruimei,Jin, Zhudan,Wang, Mingliang
, p. 24 - 27 (2018/02/28)
A convenient and economical one-pot synthesis of a series of new 1-aryl-substituted 4-iodopyrazole-3-ols from easily available pyrazolidin- 3-ones in the presence of sodium iodide, 30% solution of hydrogen peroxide and a catalytic amount of sulfuric acid in dichloromethane via aromatisation and oxidative iodination reactions are described. This protocol has the advantages of high atom economy, costeffectiveness, short reaction time and environmental friendliness.
Direct amination of homoenolates catalyzed by N-heterocyclic carbenes
Chan, Audrey,Scheidt, Karl A.
, p. 2740 - 2741 (2008/09/19)
N-Heterocyclic carbenes derived from N-mesityl-N-methyltriazolium salts are effective catalysts for generating homoenolate species from α,β-unsaturated aldehydes. The unique intermediate adds to the electrophilic nitrogen of 1-acyl-2-aryldiazenes, and the