612091-97-1Relevant articles and documents
Ring-opening metathesis polymerization using alkenyl sulfides as chain-transfer agents: Efficient route to unsymmetrical poly(norbornene)-based macroinitiators bearing a terminal hydroxy group
Katayama, Hiroyuki,Fukuse, Yosuke,Nobuto, Yuko,Akamatsu, Kensuke,Ozawa, Fumiyuki
, p. 7020 - 7026 (2007/10/03)
Convenient routes to hydroxy-terminated poly(norbornene)s (PNBEs) have been developed. Hydroboration of PNBEs bearing a terminal vinyl group with 9-BBN followed by oxidation with H2O2/ NaOH forms of hydroxy-terminated PNBEs in high yields. The parent PNBEs are prepared by ring-opening metathesis polymerization (ROMP) of norbornene using vinylic sulfides as chain-transfer agents (CTAs). On the other hand, ROMP of norbornene using (Z)-1-phenylthio-1-propen-3-ol as a CTA causes one-step synthesis of ω-hydroxy-terminated PNBE, where the molecular weight of polymer depends linearly on the initial feed ratio of CTA to monomer. Similarly, ROMP reactions using (Z)-1-phenylthio-1-propen-3-ols having bromo, amino, and 4-(chloromethyl)benzamido substituents at the para position of the phenyl group as CTAs afford the corresponding α,ω-heterodifunctionalized (heterotelechelic) PNBEs. The resulting PNBEs serve as macroinitiators for anionic ring-opening polymerization (AROP) of εcaprolactone and atom-transfer radical polymerization (ATRP) of styrene, giving AB- and ABC-type block copolymers.
