61214-59-3

Basic information

• Product Name: 1,1-(PPh₃)2-1-H-1,2,4-IrC₂B₈H₁₀
• Synonyms: 1,1-(PPh₃)2-1-H-1,2,4-IrC₂B₈H₁₀
• CAS NO: 61214-59-3
• Molecular Weight: 838.399
• Mol File: 61214-59-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1-(PPh₃)2-1-H-1,2,4-IrC₂B₈H₁₀(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-(PPh₃)2-1-H-1,2,4-IrC₂B₈H₁₀(61214-59-3)
• EPA Substance Registry System: 1,1-(PPh₃)2-1-H-1,2,4-IrC₂B₈H₁₀(61214-59-3)

Safety Data

• Hazardous Substances Data: 61214-59-3(Hazardous Substances Data)

Upstream product

• 16070-58-9 tris(triphenylphosphine)chloroiridium 
• 16070-58-9 [Ir(PPh₃)₃Cl] 

Relevant articles and documents

Eleven-Vertex Rhodium, Iridium, and Ruthenium Phosphinometallocarborane Complexes Formed from Sodium Undecahydro-5,6-dicarba-nido-decaborate(1-)

Reactions of sodium undecahydro-5,6-dicarba-nido-decaborate(1-) (NaC2B8H11) with n> (n = 2, L = P(CH3)2Ph, As(CH3)2Ph; n = 3, L = PPh3) afforded the 18e- IrIII complexes , while reaction with produced the 16e- RhI complexes (L = PPh3, P(p-tolyl)3) and the 18e- RhI complexes (L = As(CH3)2Ph, P(CH3)2Ph, P(CH3)3, As(CH3)3, Sb(CH3)3, PEt3).In solution, dissociates triethylphosphine reversibly to form , which partially isomerizes to upon standing.The standard enthalpy and entropy of formation of from are -3.1 +/- 0.1 kcal mol-1 and -10.5 +/- 0.4 eu, respectively.The reaction of NaC2B8H11 with yielded , in which a PPh3 ligand has displaced a terminal B-H hydrogen atom of the carborane ligand.