61358-15-4

Basic information

• Product Name: 1,5-Dithiocane, 1-oxide
• CAS NO: 61358-15-4
• Molecular Formula: C6H12OS2
• Molecular Weight: 164.293
• Mol File: 61358-15-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,5-Dithiocane, 1-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-Dithiocane, 1-oxide(61358-15-4)
• EPA Substance Registry System: 1,5-Dithiocane, 1-oxide(61358-15-4)

Safety Data

• Hazardous Substances Data: 61358-15-4(Hazardous Substances Data)

Upstream product

• 6572-95-8 1,5-dithiocane 
• 603-34-9 N,N-diphenylaminobenzene 
• 113504-08-8 1,5-dithioniabicyclo<3.3.0>octane bis(trifluoromethanesulphonate) 
• 733-90-4 trityllithium 
• 82438-50-4 9-fluorenyllithium 
• 30043-41-5 (hex-5-enyl)magnesium bromide 
• 126524-57-0 9-mesitylfluorenyllithium 
• 62-53-3 aniline 
• 122-66-7 diphenyl hydrazine 

Downstream Products

• 117007-60-0 1-(4-hydroxyphenyl)-1-thionia-5-thiacyclooctane trifluoromethanesulfonate 

Relevant articles and documents

Photooxidation of 1,5-dithiacyclooctane. A novel C-S bond cleavage

Sensitized photooxidation of 1,5-dithiacyclooctane (1,5-DTCO) has been investigated in various solvents. At high conversions, a novel C-S bond cleavage occurs. Significant solvent effects are also observed. At high concentration (0.05-0.1 M) in methanol, more than 90% of the corresponding monosulfoxide and a mixture of cis- and trans-bissulfoxides are produced. In aprotic solvents (benzene, chloroform, acetone, and acetonitrile), novel cleavage products (1,2-dithiolane 1-oxide, 1,2-dithiolane 1,1-dioxide, and acrolein) were obtained in addition to the monosulfoxide and bissulfoxides. The cleavage products derive mostly from reaction of the primary monosulfoxide (1,5-DTCO 1-oxide) with singlet oxygen. Unstable compounds oxidized α to the sulfur atom were detected by NMR spectroscopy and shown to be intermediate in the formation of the cleavage products.

A New Mode of Aromatic Substitution and Redox Reaction of Substituted Benzenes with Disulfide Dication: 1,5-Dithioniabicyclooctane Bis(trifluoromethanesulfonate)

Disulfide dication was found to react with several aromatics to give either the substitution or redox products.The rection mode depends remarkably on the oxidation potential of the aromatics.