61388-91-8Relevant articles and documents
Regioselective remote C5 cyanoalkoxylation and cyanoalkylation of 8-aminoquinolines with azobisisobutyronitrile
Wen, Chunxia,Zhong, Ronglin,Qin, Zengxin,Zhao, Mengfei,Li, Jizhen
supporting information, p. 9529 - 9532 (2020/09/03)
The efficient regioselective C-H cyanoalkoxylation and cyanoalkylation of 8-aminoquinoline derivatives at the C5 position have been achieved under O2 and N2 atmospheres, respectively. Using 2,2′-azobisisobutyronitrile (AIBN) as a radical precursor, the pr
Iron-Catalyzed Regioselective Remote C(sp2)-H Carboxylation of Naphthyl and Quinoline Amides
Kumar, Sandeep,Pradhan, Sourav,Roy, Subhasish,De, Pinaki Bhusan,Punniyamurthy, Tharmalingam
, p. 10481 - 10489 (2019/08/20)
Iron(III)-catalyzed regioselective direct remote C-H carboxylation of naphthyl and quinoline amides was developed using CBr4 and alcohol. The reaction involves a radical pathway using a coordination activation strategy and single electron transfer process. The use of sustainable iron catalysis, selectivity, and the substrate scope are the important practical features.
Direct oxytosylation of 8-amidoquinolines by koser's reagent: An efficient strategy for 5-substituted 8-amidoquinolines
Begum, Zubeda,Bhavani,Sridhar,Reddy, Basireddy V. Subba
, p. 4089 - 4096 (2018/10/15)
A metal-free remote oxytosylation of 8-amidoquinolines has been achieved using Koser's reagent to produce 5-tosyloxy-8-amidoquinolines in good yields. This method is compatible with various functional groups present on the aromatic ring.