61589-64-8

Basic information

• Product Name: 1-Undecene, 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-
• CAS NO: 61589-64-8
• Molecular Formula: C11H5F17
• Molecular Weight: 460.134
• Mol File: 61589-64-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1-Undecene, 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Undecene, 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-(61589-64-8)
• EPA Substance Registry System: 1-Undecene, 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoro-(61589-64-8)

Safety Data

• Hazardous Substances Data: 61589-64-8(Hazardous Substances Data)

Upstream product

• 187737-37-7 propene 
• 77758-89-5 phenyl(perfluorooctyl)iodonium triflate 
• 68555-67-9 Sodium n-perfluorooctanesulfinate 
• 106-95-6 allyl bromide 
• 556-56-9 allyl iodid 
• 507-63-1 1-iodoheptadecafluorooctane 
• 38550-45-7 3-perfluoro-n-octyl-2-iodo-1-propanol 
• 107-05-1 3-chloroprop-1-ene 

Downstream Products

• 1228259-52-6 1-bromo-4-(4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heptadecafluoroundec-1-enyl)benzene 
• 879286-78-9 (P(C₆H₅)2C₃H₆P(C₆H₅)2)Pd(OCCH₃CH₂CHCH₂C₈F₁₇)⁽¹⁺⁾*B(C₆H₃(CF₃)2)4^(1-)=P₂(C₆H₅)4C₃H₆PdOCCH₃CH₂CHCH₂C₈F₁₇B(C₆H₃(CF₃)2)4 

Relevant articles and documents

Syntheses of fluorous propenes from 3-perfluoroalkyl-2-iodo-1-propanols

3-(Perfluoroalkyl)-1-propenes are obtained in excellent yields up to 100-g quantities by deiodination-dehydroxylation reactions of the easily accessible 2-iodo-3-(perfluoroalkyl)-propanols with red phosphorus and catalytic amounts of iodine or with an SnCl2/POCl3 reagent pair in pyridine (fluorous Cornforth reaction). Both methods afford fluorous propenes in high GC purity, the former one has high atom-economy and proceeds safely if the fluorous iodohydrin precursors are added in increments; for the solid ones using a 'hot-melt' dropping funnel. The title fluorous propenes are effectively isolated by co-distillation with pyridine.

Reaction of Perfluoroalkanesulfinates with Allyl and Propargyl Halides. A Convenient Synthesis of 3-(Perfluoroalkyl)prop-1-enes and 3-(Perfluoroalkyl)allenes

The reaction of perfluoroalkanesulfinates, RfCF2SO2Na, with allyl and propargyl halides, in the presence of (NH4)2S2O8, gave 3-(perfluoroalkyl)prop-1-enes (RfCH2CH=CH2) and 3-(perfluoroalkyl)allenes (RfCH=C=CH2), respectively, in good yield.Evidence is presented for a radical addition-elimination mechanism for the reaction.The reaction represents a synthetically viable and convenient route to such compounds.