6160-49-2

Basic information

• Product Name: 1-O-acetyl-3,5-di-O-benzyl-2-deoxy-D-erythro-pentofuranose
• Synonyms: 1-O-acetyl-3,5-di-O-benzyl-2-deoxy-D-erythro-pentofuranose
• CAS NO: 6160-49-2
• Molecular Weight: 356.419
• Mol File: 6160-49-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-O-acetyl-3,5-di-O-benzyl-2-deoxy-D-erythro-pentofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1-O-acetyl-3,5-di-O-benzyl-2-deoxy-D-erythro-pentofuranose(6160-49-2)
• EPA Substance Registry System: 1-O-acetyl-3,5-di-O-benzyl-2-deoxy-D-erythro-pentofuranose(6160-49-2)

Safety Data

• Hazardous Substances Data: 6160-49-2(Hazardous Substances Data)

Upstream product

• 132487-16-2 methyl 3,5-di-O-benzyl-2-deoxy-D-ribofuranoside 
• 100-39-0 benzyl bromide 
• 51255-17-5 1-O-methyl-2-deoxy-D-ribofuranoside 
• 100-44-7 benzyl chloride 
• 6160-50-5 3,5-di-O-benzyl-2-deoxy-D-ribofuranose 
• 108-24-7 acetic anhydride 

Downstream Products

• 226232-79-7 3,5-Di-O-benzyl-2-desoxy-β-D-ribofuranose-1-imidocarbonsaeuremethylester 
• 226232-77-5 3,5-Di-O-benzyl-2-desoxy-α-D-ribofuranose-1-imidocarbonsaeuremethylester 
• 226232-83-3 5-(3',5'-Di-O-benzyl-2'-desoxy-β-D-ribofuranosyl)-3,6-bis(trifluoromethyl)-1,2,4-triazin 
• 226232-81-1 5-(3',5'-Di-O-benzyl-2'-desoxy-α-D-ribofuranosyl)-3,6-bis(trifluoromethyl)-1,2,4-triazin 
• 137121-87-0 α/β-D-thymidine 
• 78138-02-0 1-(3,5-di-O-benzyl-2-deoxy-α,β-D-erythro-pentofuranosyl)thymine 
• 78138-03-1 1-(3,5-di-O-benzyl-2-deoxy-α-D-erythro-pentofuranosyl)thymine 
• 78138-00-8 1-<3,5-di-O-benzyl-2-deoxy-α,β-D-erythro-pentofuranosyl>-5,6-dihydro-5-N-methyl-s-triazine-2,4-(3H)-dione 
• 1200119-13-6 3,5-di-O-benzyl-2-deoxy-α-D-ribofuranosyl azide 
• 154096-13-6 (2R,3S)-3-(benzyloxy)-2-((benzyloxy)methyl)-2,3-dihydrofuran 
• 170983-98-9 1β-cyano-3,5-di-O-benzyl-1,2-dideoxy-D-ribofuranose 
• 1057653-80-1 4,7-anhydro-6,7-di-O-benzyl-1,2,3,5-tetradeoxy-D-ribo-oct-1-enitol 
• 259877-34-4 (2R,3S,5R)-5-allyl-3-(benzyloxy)-2-((benzyloxy)methyl)-tetrahydrofuran 
• 226232-74-2 1α-cyano-3,5-di-O-benzyl-1,2-dideoxy-D-ribofuranose 

Relevant articles and documents

Synthesis of novel Pyridine-, Pyrindine- and Isoquinoline-substituted α- and β-C-nucleosides of 2-deoxy-D-ribose

The novel imido esters of 2-deoxy-α- and -β-D-ribose 8 and 9 have been synthesized and successfully transformed to the protected 1,2,4-triazine-C-nucleosides 11 and 12 using an inverse type Diels-Alder reaction with the 1,2,4,5-tetrazine 10. The electron deficient diazadiene system of both C-nucleosides 11 and 12 proved to be highly reactive in a consecutive [4 + 2] cycloaddition with inverse electron demand towards several electron rich dienophiles yielding after successful deprotection the novel pyridine-, pyrindine- and isoquinoline-C-nucleosides 15, 18 and 21 of 2-deoxy-α-D-ribose and 23, 25 and 27 of 2-deoxy-β-D-ribose.

STEREOCHEMICAL CONTROL AS A FUNCTION OF PROTECTING-GROUP PARTICIPATION IN 2-DEOXY-D-ERYTHRO-PENTOFURANOSYL NUCLEOSIDES

Possible features controlling the anomeric ratios in the synthesis of the antiviral antibiotic dihydro-5-azathymidine have been examined.Replacement of the 3- and 5-(4-methylbenzoyl) protecting groups in 2-deoxy-D-erythro-pentofuranosyl chloride by benzyl