616207-86-4

Basic information

• Product Name: (Z)-(4R,7S)-7-Benzyloxymethyl-5-methyl-nona-1,5-dien-4-ol
• Synonyms: (Z)-(4R,7S)-7-Benzyloxymethyl-5-methyl-nona-1,5-dien-4-ol
• CAS NO: 616207-86-4
• Molecular Weight: 274.403
• Mol File: 616207-86-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-(4R,7S)-7-Benzyloxymethyl-5-methyl-nona-1,5-dien-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-(4R,7S)-7-Benzyloxymethyl-5-methyl-nona-1,5-dien-4-ol(616207-86-4)
• EPA Substance Registry System: (Z)-(4R,7S)-7-Benzyloxymethyl-5-methyl-nona-1,5-dien-4-ol(616207-86-4)

Safety Data

• Hazardous Substances Data: 616207-86-4(Hazardous Substances Data)

Upstream product

• 106356-53-0 B-allyldiisopinocampheylborane 
• 1025799-90-9 (Z)-(S)-4-Benzyloxymethyl-2-methyl-hex-2-enal 
• 616207-85-3 (Z)-(S)-4-Benzyloxymethyl-2-methyl-hex-2-enoic acid ethyl ester 
• 616207-93-3 (Z)-(S)-4-Benzyloxymethyl-2-methyl-hex-2-en-1-ol 
• 3587-60-8 Benzyloxymethyl chloride 
• 163457-34-9 (+)-(4S)-3-<(2'R)-2'-((benzyloxy)methyl)butanoyl>-4-benzyl-2-oxazolidinone 
• 916501-75-2 2-<(benzyloxy)-methyl>butyraldehyde 

Downstream Products

• 616207-90-0 (4S,6R)-6-((Z)-(S)-3-Benzyloxymethyl-1-methyl-pent-1-enyl)-4-(tert-butyl-diphenyl-silanyloxy)-tetrahydro-pyran-2-one 
• 616207-89-7 (4S,6R)-6-((Z)-(S)-3-Benzyloxymethyl-1-methyl-pent-1-enyl)-4-hydroxy-tetrahydro-pyran-2-one 
• 616207-88-6 (R)-6-((Z)-(S)-3-Benzyloxymethyl-1-methyl-pent-1-enyl)-5,6-dihydro-pyran-2-one 
• 616207-87-5 Acrylic acid (Z)-(1R,4S)-1-allyl-4-benzyloxymethyl-2-methyl-hex-2-enyl ester 

Relevant articles and documents

Synthetic studies of microtubule stabilizing agent peloruside A: An asymmetric synthesis of C10-C24 segment

An asymmetric synthesis of the C10-C24 fragment of the potent antitumor macrolide, peloruside A is described. All three stereogenic centers have been enantioselectively constructed utilizing Evans alkylation, Brown asymmetric allylboration, and a substrate controlled epoxide formation. Other key reactions involved Grubbs's ring-closing olefin metathesis and Ando's Z-selective olefination reaction.