616227-10-2

Basic information

• Product Name: 2-nitro-6-methylphenylboronic acid (+)-pinanediol ester
• Synonyms: 2-nitro-6-methylphenylboronic acid (+)-pinanediol ester
• CAS NO: 616227-10-2
• Molecular Weight: 315.177
• Mol File: 616227-10-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-nitro-6-methylphenylboronic acid (+)-pinanediol ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-nitro-6-methylphenylboronic acid (+)-pinanediol ester(616227-10-2)
• EPA Substance Registry System: 2-nitro-6-methylphenylboronic acid (+)-pinanediol ester(616227-10-2)

Safety Data

• Hazardous Substances Data: 616227-10-2(Hazardous Substances Data)

Upstream product

• 41085-43-2 2-bromo-3-nitrotoluene 
• 18680-27-8 pinanediol 
• 616227-09-9 2-nitro-6-methylphenylboronic acid neopentylglycol ester 

Downstream Products

• 669064-44-2 2-amino-6-methylphenylboronic acid (+)-pinanediol ester 

Relevant articles and documents

Design of chiral boronate-substituted acrylanilides. Self-activation and boron-transmitted 1,8-stereoinduction in [4+2] cycloaddition

The [4+2] cycloaddition of ortho-boronoanilide dienophile 4 with cyclopentadiene was found to proceed faster than both its para isomer 8 and the unsubstituted derivative 6, thereby confirming that self-activation by internal coordination is operative in the case of 4. Chiral boronic esters derivatives 9-13 provided a small level of remote 1,8-stereoinduction transmitted through a putative tetrahedral stereogenic boronate complex. These results show that dialkoxyboronic esters can operate as weak, internal Lewis acids and activate carbonyl-containing functionalities in cycloaddition reactions.