61633-06-5Relevant articles and documents
Cyclometallation Reactions of 6-Phenyl-2,2'-bipyridine, a Potential C,N,N-Donor Analogue of 2,2':6',2''-Terpyridine. Crystal and Molecular Structure of Dichlorobis(6-phenyl-2,2'-bipyridine)ruthenium(II)
Constable, Edwin C.,Henney, Roland P. G.,Leese, Troy A.,Tocher, Derek A.
, p. 443 - 449 (1990)
Metallated and non-metallated complexes of the ligand 6-phenyl-2,2'-bipyridine (HL) with ruthenium(II), rhodium(III), platinum(II), palladium(II), and gold(III) have been prepared.The crystal and molecular structure of the complex indicates that it contains two N-bonded ligands and a cis arrangement of the chlorides.
The cyclometalated nickel complex [(Phbpy)NiBr] (Phbpy- = 2,2′-bipyridine-6-phen-2-yl) - Synthesis, spectroscopic and electrochemical studies
Klein, Axel,Rausch, Benjamin,Kaiser, Andre,Vogt, Nicolas,Krest, Alexander
, p. 86 - 93 (2014)
The new organometallic nickel complex [(Phbpy)NiBr] containing the anionic tridentate N,N,C ligand 6-(phen-2-yl)-2,2′-bipyridine (Phbpy-) was synthesised from PhbpyBr and [Ni(COD)2] in excellent yields and was fully characterised (MS
Highly phosphorescent organopalladium(ii) complexes with metal-metal-to-ligand charge-transfer excited states in fluid solutions
Lin, Jinqiang,Zou, Chao,Zhang, Xiaobao,Gao, Qin,Suo, Sa,Zhuo, Qihang,Chang, Xiaoyong,Xie, Mo,Lu, Wei
supporting information, p. 10417 - 10421 (2019/07/22)
Dinuclear pincer-type cyclometalated Pd(ii) complexes with foldable diacetylide ligands show crystallographically determined intramolecular Pd?Pd contacts of 3.203-3.380 ?. In deoxygenated fluid solutions, these Pd(ii) complexes are highly phosphorescent
Iron catalyzed oxidative assembly of N-heteroaryl and aryl metal reagents using oxygen as an oxidant
Liu, Kun Ming,Liao, Lian Yan,Duan, Xin Fang
supporting information, p. 1124 - 1127 (2015/01/09)
An equivalent amount of N-heteroaryl and aryl Grignard or lithium reagents, after mediation by an equivalent of titanate, was facilely coupled to furnish N-heteroaryl-aryl compounds under the catalysis of FeCl3/TMEDA at ambient temperature using oxygen as an oxidant. Most of the common N-heteroaryls were all good candidates, and thus provided a general, green and pratical protocol for the flexible construction of various N-heteroaryl-aryl structures. This journal is