61759-13-5

Basic information

• Product Name: 2-Propanone, 1-(phenylseleno)-
• CAS NO: 61759-13-5
• Molecular Formula: C9H10OSe
• Molecular Weight: 213.138
• Mol File: 61759-13-5.mol
• Article Data: 26

Chemical Properties

• CAS DataBase Reference: 2-Propanone, 1-(phenylseleno)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propanone, 1-(phenylseleno)-(61759-13-5)
• EPA Substance Registry System: 2-Propanone, 1-(phenylseleno)-(61759-13-5)

Safety Data

• Hazardous Substances Data: 61759-13-5(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 645-96-5 Benzeneselenol 
• 78-95-5 chloroacetone 
• 1666-13-3 diphenyl diselenide 
• 598-31-2 1-bromoacetone 
• 71338-47-1 2-phenylselenoacetaldehyde diethylacetal 
• 71338-48-2 phenylselanylacetaldehyde 
• 34837-55-3 Phenylselenyl bromide 
• 42572-42-9 phenylselenium trichloride 
• 71098-88-9 N-phenylselanylphthalimide 
• 67-64-1 acetone 
• 199535-61-0 2,5-dimethoxy-3-phenylselanyl-2,5-dihydrofuran 
• 186581-53-3 diazomethane 
• 30876-65-4 2-phenyl-1-(phenylseleno)ethanone 

Downstream Products

• 14370-82-2 allyl phenyl selenide 
• 191099-37-3 3-(phenylselanyl)hex-5-en-2-one 
• 59085-70-0 2-methyl-3-prop-2-enyl phenylselenide 
• 281669-95-2 N-allyl-N-diphenylphosphinoyl-2-aminopropyl phenyl selenide 
• 281670-02-8 N-allyl-2-aminopropyl phenyl selenide 
• 263262-52-8 N-benzyl-1-(phenylselanyl)propan-2-amine 
• 831200-91-0 N-benzyl-2-methyl-1-(phenylselanyl)pent-4-en-2-amine 
• 831200-77-2 phenyl-N-(1-(phenylselanyl)propan-2-ylidene)methanamine 
• 194613-69-9 (E)-3-Methyl-4-phenylselanyl-but-2-enoic acid benzyl ester 
• 72726-46-6 tert-butyl(dimethyl)(phenylseleno)silane 

Relevant articles and documents

Preparation of selenofunctionalized heterocycles via iodosobenzene-mediated intramolecular selenocyclizations of olefins with diselenides

An intramolecular selenocyclizations of olefins mediated by a commercially available hypervalent iodine(III) reagent, PhIO, was developed. This method provided access to a wide range of selenenylated heterocycles under ambient conditions. The striking advantages of this protocol over all previous methods include mild reaction conditions, easy operation, good yields, high levels of functional group compatibility, large–scale application and suitability for the late-stage functionalization of complex molecules of biological importance.

O-(tert-butyl) Se-phenyl selenocarbonate: A convenient, bench-stable and metal-free precursor of benzeneselenol

A study by our laboratory shows that air, light and moisture stable O-(tert-butyl) Se-phenyl selenocarbonate could be employed as a safer, practical and efficient alternative to generate “in situ” benzeneselenol or benzeneselenolate anion under different and transition metal-free conditions. This procedure seems to be of general application since the nucleophilic selenium species obtained can be trapped by electrophiles such as alkyl halides, epoxides and electron-deficient alkenes and alkynes under different reaction conditions.

Rhodium-Catalyzed Rearrangement of S/Se-Ylides for the Synthesis of Substituted Vinylogous Carbonates

An efficient rhodium-catalyzed unprecedented oxa-[2,3]-sigmatropic rearrangement of sulfur ylide derived from α-thioesters/ketones and diazo carbonyl compounds has been accomplished for the synthesis of various sulfur-tethered vinylogous carbonates in good to excellent yields. Important features of the developed reaction include wide functional group tolerance, excellent chemo- and regioselectivity, and efficient rearrangement involving the carbonyl motif. The present reaction also equally works well with α-selenoesters for the synthesis of seleno-containing vinylogous carbonates.