6186-89-6Relevant articles and documents
One-by-one hydrogenation, cross-coupling reaction, and Knoevenagel condensations catalyzed by PdCl2 and the downstream palladium residue
Wang, Hu,Li, Li,Bai, Xing-Feng,Deng, Wen-Hui,Zheng, Zhan-Jiang,Yang, Ke-Fang,Xu, Li-Wen
supporting information, p. 2349 - 2355 (2013/09/12)
A novel catalyst-economic strategy with a recovered palladium catalyst was successfully applied for multi-task and maximum reuse in different types of one-by-one downstream reactions, from catalytic hydrogenation to Suzuki and Sonogashira-type cross-coupling reactions, Knoevenagel condensations, and trans-Knoevenagel-like condensations.
Synthesis of 2/6-(polychloromethyl)pyridinecarboxylates
Chupp, John P.,Smith, Lowell R.
, p. 1785 - 1792 (2007/10/02)
Due to their relationship to certain bio-active 2,6-(polyfluoromethyl)-3,5-pyridinedicarboxylates 12, methodology was developed to prepare new, but analogous 2/6 (polychloromethyl)pyridinecarboxylates 6, 9, 10, 13, 18 and 20.Successful methods to prepare these materials include several chlorination procedures, mixed Hantzsch sequences, and aluminium chloride interchanges with 12 and 16.
ALKYLCOBALT CARBONYLS. VI. REACTION OF COBALT TETRACARBONYL WITH I2 DISSOLVED IN MeOH
Tasi, Miklos,Galamb, Vilmos,Palyi, Gyula
, p. C31 - C33 (2007/10/02)
Reaction of EtOOCCH2Co(CO)4 with I2 dissolved in MeOH yields XCH2COOEt (X=H, I, COOMe): the product with X=COOMe was formed even in the reaction in Ar.