61955-86-0

Basic information

• Product Name: 2-Butanone, 1-(acetyloxy)-4-phenyl-4-(phenylthio)-
• CAS NO: 61955-86-0
• Molecular Formula: C18H18O3S
• Molecular Weight: 314.405
• Mol File: 61955-86-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 1-(acetyloxy)-4-phenyl-4-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 1-(acetyloxy)-4-phenyl-4-(phenylthio)-(61955-86-0)
• EPA Substance Registry System: 2-Butanone, 1-(acetyloxy)-4-phenyl-4-(phenylthio)-(61955-86-0)

Safety Data

• Hazardous Substances Data: 61955-86-0(Hazardous Substances Data)

Upstream product

• 61955-78-0 3-Phenyl-3-phenylthiopropionylchlorid 
• 5425-50-3 3-phenyl-3-(phenylmercapto)propanoic acid 
• 61955-79-1 1-Chlor-4-phenyl-4-phenylthio-2-butanon 
• 88981-42-4 Chloromethyl styryl ketone 
• 118487-52-8 (E)-2-oxo-4-phenylbut-3-en-1-yl acetate 
• 108-98-5 thiophenol 
• 64-19-7 acetic acid 
• 127-08-2 potassium acetate 

Relevant articles and documents

REACTIONS OF α-DIAZO KETONES. IV. S-5 PARTICIPATION AND β-ELIMINATION IN THE ACETOLYSIS OF 4-ARYLTHIO- AND 4-ARALKYLTHIO-1-DIAZO-2-BUTANONES

The acetolyses of α-diazo ketones 2a-d, bearing a thioether group on the β'-carbon have been studied in neat AcOH and in the presence of acetate.All these reactions lead to products arising from the 1,4-shift of the thioether group, normal substitution being only a secondary pathway, particularly in the case of 2d, which almost exclusively undergoes fragmentation to benzhydryl acetate and 3-oxotetrahydrothiophene.The mechanisms involved are discussed.