61967-11-1Relevant articles and documents
Regio- and stereoselective preparation of highly substituted tertiary homoallylic alcohols
Takeda, Takeshi,Wasa, Hideki,Tsubouchi, Akira
, p. 4575 - 4578 (2011)
The titanocene(II)-promoted reaction of α-(benzyldimethylsilyl) allylic sulfides with ketones proceeded with high regio- and stereoselectivity to give δ-silylhomoallylic alcohols. The following palladium catalyzed cross-couplings with organic halides prod
Direct use of 1,3-dienes for the allylation of ketones: Via catalytic hydroindation
Miyamoto, Shinji,Shibata, Ikuya,Suzuki, Itaru,Yagi, Kensuke
, p. 6030 - 6034 (2020/02/26)
In this study, in situ catalytically generated allylic indium from 1,3 dienes and InCl2H was developed for use in the allylation of ketones. This protocol resulted in the unprecedented establishment of a successive combining of quaternary C-C b
Synthesis of highly substituted indene derivatives by Br?nsted acid catalyzed Friedel-Crafts reaction of homoallylic alcohols
Zhang, Xiaoxiang,Teo, Wan Teng,Rao, Weidong,Ma, Dik-Lung,Leung, Chung-Hang,Chan, Philip Wai Hong
supporting information, p. 3881 - 3884 (2014/07/08)
An efficient synthetic method to prepare highly substituted indenes in moderate to excellent yields that relies on Br?nsted acid catalyzed Friedel-Crafts reaction of homoallylic alcohols under mild conditions is described.