62030-43-7Relevant articles and documents
Chromium(III) octaethylporphyrinato tetracarbonylcobaltate: A highly active, selective, and versatile catalyst for epoxide carbonylation
Schmidt, Joseph A. R.,Lobkovsky, Emil B.,Coates, Geoffrey W.
, p. 11426 - 11435 (2007/10/03)
The development of a highly active and selective porphyrin-based epoxide carbonylation catalyst, [(OEP)Cr(THF)2][Co(CO)4] (1; OEP = octaethylporphyrinato; THF = tetrahydrofuran), is detailed. Complex 1 is a separated ion pair compose
SELECTIVE SYNTHESIS OF γ,δ-UNSATURATED CARBOXYLIC ACID DERIVATIVES BY THE NI(CO)4-INDUCED RING-OPENING CARBONYLATION REACTION
Hirao, Toshikazu,Nagata, Shinichiro,Agawa, Toshio
, p. 5795 - 5798 (2007/10/02)
gem-Dibromocyclopropanes bearing the chloromethyl or mesyloxymethyl substituent at the vicinal position underwent the Ni(CO)4-induced ring-opening carbonylation reaction with alcohol or amines leading to the γ,δ-unsaturated carboxylic acid derivatives sel