62037-81-4Relevant articles and documents
Controlled introduction of metal cations into polymerizable ionic liquid-polyoxomolybdate hybrid crystals
Kobayashi, Jun,Misawa, Toshiyuki,Umeda, Chihiro,Isono, Toru,Ono, Seiji,Naruke, Haruo,Okamura, Yosuke,Koguchi, Shinichi,Higuchi, Masashi,Nagase, Yu,Ito, Takeru
, p. 629 - 636 (2019)
A polymerizable ionic-liquid cation having methacryl group and imidazolium moieties (denoted as MAImC1) was successfully hybridized with octamolybdate (Mo8O264?, Mo8) to obtain inorganic-organic hybrid crystals containing monovalent metal cations. The hybrid crystals were initially prepared as sodium ion-containing hybrid crystal of MAImC1-Na-Mo8. The sodium cations in MAImC1-Na-Mo8 were exchangeable to other monovalent metal cations such as silver or potassium to form hybrid crystals of MAImC1-Ag-Mo8 or MAImC1-K-Mo8. Their molecular and crystal structures were clearly revealed by single crystal X-ray analyses. The MAImC1-Na-Mo8 hybrid crystal worked as the hybrid monomer, and was found polymerizable by a radical polymerization using AIBN as an initiator to obtain inorganic-organic polymers (P-MAImC1-Na-Mo8). The conductivities of the hybrid monomer and polymer consisting of MAImC1-Na-Mo8 were investigated.
NON-ENZYMATIC ELECTROCHEMICAL SENSOR FOR MEASURING ANALYTES
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Paragraph 00106; 00107, (2015/11/16)
Embodiments described herein relate generally to compositions that include a synthetic redox-active receptor, and in particular to compositions that include a boronic acid based synthetic redox-active receptor which can electrochemically sense a target analyte in a sample solution. In some embodiments, a synthetic redox-active receptor can have a composition of formula I: wherein the variables L, L', R, R' n and X are described herein.