62058-64-4

Basic information

• Product Name: (Z)-2-Aminostilbene
• Synonyms: (Z)-2-Aminostilbene
• CAS NO: 62058-64-4
• Molecular Formula: C₁₄H₁₃N
• Molecular Weight: 195.26
• Mol File: 62058-64-4.mol
• Article Data: 18

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (Z)-2-Aminostilbene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2-Aminostilbene(62058-64-4)
• EPA Substance Registry System: (Z)-2-Aminostilbene(62058-64-4)

Safety Data

• Hazardous Substances Data: 62058-64-4(Hazardous Substances Data)

Upstream product

• 35010-17-4 1-nitro-2-phenylethynyl-benzene 
• 5344-90-1 2-Aminobenzyl alcohol 
• 1449-46-3 benzyltriphenylphosphonium bromide 
• 100-39-0 benzyl bromide 
• 4714-25-4 2-nitrostilbene 
• 536-74-3 phenylacetylene 
• 13141-38-3 2-phenylethynylaniline 
• 615-43-0 2-iodophenylamine 
• 27652-35-3 (E)-2-styrylaniline 
• 100-42-5 styrene 
• 615-36-1 2-bromoaniline 
• 52208-62-5 (Z)-2-nitrostilbene 

Downstream Products

• 107734-06-5 N-tosyl-2-phenylindole 
• 948-65-2 2-phenyl-indole 
• 22514-82-5 2,3-diphenyl quinoline 
• 52604-16-7 3-(Phenylmethyl)-2-phenylindole 
• 1610967-60-6 (Z)-4-methyl-N-(2-styrylphenyl)benzenesulfonamide 
• 1610967-30-0 (Z)-N-[(2-azidophenyl)ethynyl]-4-methyl-N-(2-styrylphenyl)benzenesulfonamide 
• 89100-39-0 1-azido-2-((Z)-styryl)benzene 
• 27652-35-3 (E)-2-styrylaniline 
• 339996-08-6 C₁₈H₁₇ClN₂O₂ 
• 72592-61-1 N-(2-styrylphenyl)acetamide 
• 85-01-8 phenanthrene 

Relevant articles and documents

Copper(0) nanoparticle catalyzed Z-Selective Transfer Semihydrogenation of Internal Alkynes

The use of copper(0) nanoparticles in the transfer semihydrogenation of alkynes has been investigated as a lead-free alternative to Lindlar catalysts. A stereo-selective methodology for the hydrogenation of internal alkynes to the corresponding (Z)-alkenes in high isolated yields (86% average) has been developed. This green and sustainable transfer hydrogenation protocol relies on non-noble copper nanoparticles for reduction of both electron-rich and electron-deficient, aliphatic-substituted and aromatic- substituted internal alkynes. Polyols, such as ethylene glycol and glycerol, have been proven to act as hydrogen sources, and excellent stereo- and chemoselectivity have been observed. Enabling technologies, such as microwave and ultrasound irradiation are shown to enhance heat and mass transfer, whether used alone or in combination, resulting in a decrease in reaction time from hours to minutes. (Figure presented.).

Ruthenium-Catalyzed E-Selective Alkyne Semihydrogenation with Alcohols as Hydrogen Donors

Selective direct ruthenium-catalyzed semihydrogenation of diaryl alkynes to the corresponding E-alkenes has been achieved using alcohols as the hydrogen source. The method employs a simple ruthenium catalyst, does not require external ligands, and affords the desired products in > 99% NMR yield in most cases (up to 93% isolated yield). Best results were obtained using benzyl alcohol as the hydrogen donor, although biorenewable alcohols such as furfuryl alcohol could also be applied. In addition, tandem semihydrogenation-alkylation reactions were demonstrated, with potential applications in the synthesis of resveratrol derivatives.

Iron-Catalyzed Intramolecular Aminations of C(sp3)?H Bonds in Alkylaryl Azides

The nucleophilic iron complex Bu4N[Fe(CO)3(NO)] (TBA[Fe]) catalyzes the direct intramolecular amination of unactivated C(sp3)?H bonds in alkylaryl azides, which results in the formation of substituted indoline and tetrahydroquinoline derivatives.