62121-84-0Relevant articles and documents
Cis-fused dihydrofurano-1,2,4-trioxanes
Jefford, Charles W.,Jin, Shu-Juan,Rossier, Jean-Claude,Kohmoto, Shigeo,Bernardinelli, Gérald
, p. 367 - 378 (1997)
The endoperoxide obtained from 2,5-diphenylfuran at -30°C on catalysis with trimethylsilyl trifluoromethanesulfonate condenses with pivalaldehyde, acetone and cyclohexanone to give the corresponding cis-fused dihydrofurano-1,2,4-trioxanes (20, 21, 22 and
Palladium-catalyzed cyclopropanation of unsaturated endoperoxides. A new peroxide-preserving reaction
Emerzian, Michael A.,Davenport, William,Song, Jiangao,Li, Jim,Erden, Ihsan
experimental part, p. 999 - 1004 (2009/12/06)
Unsaturated bicyclic endoperoxides are efficiently cyclopropanated with excess diazomethane in the presence of catalytic palladium(II) acetate [Pd(OAc)2] in a stereoselective manner. This method represents a new peroxide-preserving transformati
Extreme rate acceleration by axial thiolate coordination on the isomerization of endoperoxide catalyzed by iron porphyrin
Yamane, Takehiro,Makino, Kohei,Umezawa, Naoki,Kato, Nobuki,Higuchi, Tsunehiko
supporting information; experimental part, p. 6438 - 6440 (2009/03/11)
(Chemical Equation Presented) A coordinated effort: The isomerization mechanism of prostaglandin H2 (PGH2), which is catalytically isomerized to prostacyclin or thromboxane A2 by cytochrome P450s, was investigated using a hemethiolate complex and an endoperoxide. Isomerization of endoperoxides proceeded very rapidly with this complex, whereas imidazole- or chloride-ligated heme had slight or no catalytic activity (see scheme).