62203-90-1

Basic information

• Product Name: N-Benzylene-N,N-dimethylpropane-1,3-diamine
• CAS NO: 62203-90-1
• Molecular Weight: 190.288
• Mol File: 62203-90-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: N-Benzylene-N,N-dimethylpropane-1,3-diamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Benzylene-N,N-dimethylpropane-1,3-diamine(62203-90-1)
• EPA Substance Registry System: N-Benzylene-N,N-dimethylpropane-1,3-diamine(62203-90-1)

Safety Data

• Hazardous Substances Data: 62203-90-1(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 109-55-7 1-amino-3-(dimethylamino)propane 
• 100-47-0 benzonitrile 
• 538-51-2 benzylidene phenylamine 
• 100-46-9 benzylamine 
• 780-25-6 N-benzylidene benzylamine 

Downstream Products

• 867313-15-3 C₁₂H₁₈Cl₂N₂Pt 
• 32857-22-0 N₁-benzyl-N₂,N₂-dimethylpropane-1,3-diamine 
• 1254097-54-5 C₄₁H₄₈N₂OSi 
• 141956-11-8 3-(3-Dimethylamino-propyl)-2-phenyl-thiazolidin-4-one 

Relevant articles and documents

Manganese-Catalyzed Selective Hydrogenative Cross-Coupling of Nitriles and Amines to Form Secondary Imines

Manganese complexes with tridentate PNN ligands have been synthesized as catalysts for hydrogenative cross-coupling reaction of nitriles and amines to form secondary imines. This reaction afforded a variety of unsymmetrical secondary imines in good yields with excellent selectivity. Investigation of catalyst intermediates indicated that an amido manganese complex may be the active catalyst species for this reaction. (Figure presented.).

Chemoselective organocatalytic aerobic oxidation of primary amines to secondary imines

Biomimetic aerobic oxidation of primary benzylic amines has been achieved by using a quinone catalyst. Excellent selectivity is observed for primary, unbranched benzylic amines relative to secondary/tertiary amines, branched benzylic amines, and aliphatic amines. The exquisite selectivity for benzylic amines enables oxidative self-sorting within dynamic mixtures of amines and imines to afford high yields of cross-coupled imine products.

Synthesis and reactivity of cyclometallated platinum (II) compounds containing [C,N,N′] terdentate ligands: Crystal structures of [PtCl{(CH3)2N(CH2)3NCH(4-ClC 6H3)}], [PtCl{(CH3)2N(CH 2)3NCH(2-ClC6H3)}]

The reaction of compound cis-[PtCl2(dmso)2] with ligands RCHN(CH2)3NMe2 (1a-1h) in which R is a phenyl group containing substituents such as Cl, F, Me, NO2 and MeO produced compounds [PtCl2{(CH3)2N(CH 2)3NCHR}] (2), as mixtures of Z and E isomers. When treated with an equimolar amount of sodium acetate in refluxing methanol compounds 2 gave cyclometallated platinum compounds 3 containing a terdentate [C,N,N′] ligand. The obtained compounds were fully characterized including structure determinations for compounds 3a, 3b and 3e. The effects of the substituents in the regioselectivity of the cyclometallation reaction and the reactivity of 3a and 3b with mono and bidentate phosphines were also studied.