62217-21-4Relevant articles and documents
Mechanistic investigations of the formation of TTF derivatives via the phosphonate way
Cristau,Darviche,Torreilles,Fabre
, p. 2103 - 2106 (2007/10/03)
We studied the influence of acetic acid concentration on the deamination and dephogphonylation of the adduct resulting of the nucleophilic reaction between adequate α-metalated phosphonate and imminium salt, to enhance the yield of such reactions in order to access efficiently a lot of unsymmetrical TTF derivatives. A mechanism is proposed for the formation of TTF, including steps, i1 to i7. The potential concurrent formation of phosphonate 1 and other by-products is also discussed.