62237-50-7Relevant articles and documents
Amberlyst-15: An efficient heterogeneous reusable catalyst for selective anti-Markovnikov addition of thiols to alkenes/alkynes and for thiolysis of epoxides
Lanke, Satish R.,Bhanage, Bhalchandra M.
, p. 29 - 33 (2013/08/23)
The anti-Markovnikov addition of thiols to alkenes/alkynes and thiolysis of epoxides is described using Amberlyst-15 as a selective, commercially available, inexpensive and reusable catalyst. The products like diorganyl sulphides, β-hydroxy sulphides and phenyl(styryl)sulfanes were obtained in good to excellent yields in short reaction time and with high regio-selectivity. The catalyst was reused up to five consecutive recycles without any loss in its catalytic activity. The developed methodology is a metal free protocol for C-S bond formation reaction with high atom economy.
Soluble ferrocene conjugates for incorporation into self-assembled monolayers
Yu,Chong, Yoochul,Kayyem, Jon Faiz,Gozin, Michael
, p. 2070 - 2079 (2007/10/03)
A series of phenylethynyl oligomers (I-V) possessing a ferrocene and thiol at each termini have been synthesized. These oligomers have been designed to overcome the inherent insolubility of this class of complexes by substitution at the phenyl groups with methyl and propoxy substituents. Several new reactions for preparing arenethiol-protected compounds are described. Interestingly, the generation of an arenethiol anion during base- or fluoride-catalyzed deprotection has been characterized.
