6246-96-4

Basic information

• Product Name: N-[(2E)-but-2-en-1-yl]aniline
• CAS NO: 6246-96-4
• Molecular Formula: C₁₀H₁₃N
• Molecular Weight: 147.2169
• Mol File: 6246-96-4.mol
• Article Data: 15

Chemical Properties

• Boiling Point: 242.7°C at 760 mmHg
• Flash Point: 101.3°C
• Density: 0.968g/cm³
• Vapor Pressure: 0.0335mmHg at 25°C
• Refractive Index: 1.569
• CAS DataBase Reference: N-[(2E)-but-2-en-1-yl]aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(2E)-but-2-en-1-yl]aniline(6246-96-4)
• EPA Substance Registry System: N-[(2E)-but-2-en-1-yl]aniline(6246-96-4)

Safety Data

• Hazardous Substances Data: 6246-96-4(Hazardous Substances Data)

Upstream product

• 19029-45-9 2-phenyl-3,6-dihydro-2H-[1,2]oxazine 
• 142-04-1 aniline hydrochloride 
• 106-99-0 buta-1,3-diene 
• 62-53-3 aniline 
• 542-11-0 aniline hydrobromide 
• 591-97-9 1-chloro-2-butene 
• 504-61-0 (E)-but-2-enol 
• 635-90-5 1-phenylpyrrole 
• 7647-01-0 hydrogenchloride 
• 64-17-5 ethanol 
• 53780-73-7 (Z)-4-(phenylamino)but-2-en-1-ol 
• 598-32-3 2-hydroxy-3-butene 
• 71309-67-6 but-2-enylidenephenylamine 
• 123-73-9 crotonaldehyde 

Downstream Products

• 67-63-0 isopropyl alcohol 
• 1330528-20-5 C₁₁H₁₅NO 
• 1441228-30-3 1-azido-2-(but-3-en-2-yl)benzene 
• 1326627-32-0 C₁₃H₁₅NO 
• 4828-94-8 (+/-)-2-(1'-methylallyl)aniline 
• 132704-07-5 2-(1-Chloro-ethyl)-4-(toluene-4-sulfonyl)-3,4-dihydro-2H-benzo[1,4]thiazine 
• 95338-94-6 2-deuterio-N,N'-diphenylbutane-1,3-diamine 
• 77184-27-1 (-)-(1'R,2'R)-2-(2'-methoxy-1'-methylpropyl)aniline 

Relevant articles and documents

FRUSTRATED LEWIS PAIR-IMPREGNATED POROUS MATERIALS AND USES THEREOF

Described herein are compositions composed of frustrated Lewis pairs impregnated in porous materials such as, for example, metal-organic frameworks, and their uses thereof. These compositions may allow new applications of frustrated Lewis pairs in catalysis by sequestering and protecting the frustrated Lewis pair within the nanospace of the porous material. Also provided are methods of hydrogenating an organic compound having at least one unsaturated functional group comprising using the compositions described herein.

Promoting Frustrated Lewis Pairs for Heterogeneous Chemoselective Hydrogenation via the Tailored Pore Environment within Metal–Organic Frameworks

Frustrated Lewis pairs (FLPs) have recently been advanced as efficient metal-free catalysts for catalytic hydrogenation, but their performance in chemoselective hydrogenation, particularly in heterogeneous systems, has not yet been achieved. Herein, we demonstrate that, via tailoring the pore environment within metal–organic frameworks (MOFs), FLPs not only can be stabilized but also can develop interesting performance in the chemoselective hydrogenation of α,β-unsaturated organic compounds, which cannot be achieved with FLPs in a homogeneous system. Using hydrogen gas under moderate pressure, the FLP anchored within a MOF that features open metal sites and hydroxy groups on the pore walls can serve as a highly efficient heterogeneous catalyst to selectively reduce the imine bond in α,β-unsaturated imine substrates to afford unsaturated amine compounds.

A computationally designed titanium-mediated amination of allylic alcohols for the synthesis of secondary allylamines

A computational design was inspired by previous mechanistic studies and the DFT-guided reactions were implemented in the synthesis of secondary allylamines. The participation of titanium imido intermediates facilitated the reaction and the closed transiti