6249-81-6

Basic information

• Product Name: Benzeneethanol, a-methyl-b-methylene-
• CAS NO: 6249-81-6
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Mol File: 6249-81-6.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzeneethanol, a-methyl-b-methylene-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneethanol, a-methyl-b-methylene-(6249-81-6)
• EPA Substance Registry System: Benzeneethanol, a-methyl-b-methylene-(6249-81-6)

Safety Data

• Hazardous Substances Data: 6249-81-6(Hazardous Substances Data)

Upstream product

• 4432-63-7 2-phenylacrolein 
• 75-16-1 methylmagnesium bromide 
• 75-07-0 acetaldehyde 
• 98-81-7 1-bromovinylbenzene 
• 67300-99-6 1-phenylethenylmagnesium bromide 
• 6084-17-9 2-chloro-1-phenylpropan-1-one 
• 16812-43-4 bis(trimethylstannyl)methane 
• 536-74-3 phenylacetylene 
• 32123-84-5 3-phenylbut-3-en-2-one 
• 103-79-7 1-phenyl-acetone 
• 75-05-8 acetonitrile 
• 4436-22-0 1-phenylpropylene oxide 
• 598-32-3 2-hydroxy-3-butene 
• 591-50-4 iodobenzene 

Downstream Products

• 2288-18-8 2-phenyl-1,3-butadiene 
• 90173-08-3 (Z)-4-Phenyl-hex-4-enoic acid methyl ester 
• 129646-78-2 (S)-(+)-3-phenyl-3-buten-2-ol 
• 129571-70-6 Acetic acid (R)-1-methyl-2-phenyl-allyl ester 
• 192569-20-3 (E)-N-tert-Butoxycarbonyl-N-(2-phenylbut-2-enyl)benzylamine 
• 769-59-5 3-phenyl-butan-2-one 
• 40960-66-5 rac-(2R,3R)-3-phenylbutan-2-ol 
• 56907-39-2 rac-(2R,3S)-3-phenylbutan-2-ol 
• 121887-37-4 1-(1-hydroxyethyl)-1-phenylcyclopropane 
• 92-92-2 biphenyl-4-carboxylic acid 

Relevant articles and documents

Selective Aerobic Oxygenation of Tertiary Allylic Alcohols with Molecular Oxygen

Aerobic epoxidation of tertiary allylic alcohols remains a significant challenge. Reported here is an efficient and highly chemoselective copper-catalyzed epoxidation and semipinacol rearrangement reaction of tertiary allylic alcohols with molecular oxygen. The solvent 1,4-dioxane activates dioxygen, thereby precluding the addition of a sacrificial reductant.

Nonenzymatic kinetic resolution of α-aryl substituted allylic alcohols catalyzed by acyl transfer catalyst Np-PIQ

Chiral α-aryl substituted allylic alcohols are important versatile synthetic intermediates. We report here an effective nonenzymatic kinetic resolution of racemic α-aryl substituted allylic alcohols by introducing different aryl groups with acyl transfer

C2-symmetric cyclic selenium-catalyzed enantioselective bromoaminocyclization

A catalytic asymmetric bromocyclization of trisubstituted olefinic amides that uses a C2-symmetric mannitol-derived cyclic selenium catalyst and a stoichiometric amount of N-bromophthalimide is reported. The resulting enantioenriched pyrrolidine products, which contain two stereogenic centers, can undergo rearrangement to yield 2,3-disubstituted piperidines with excellent diastereoselectivity and enantiospecificity.