62499-15-4Relevant articles and documents
Comparison of the Thermal Stabilities of Diazonium Salts and Their Corresponding Triazenes
Schotten, Christiane,Leprevost, Samy K.,Yong, Low Ming,Hughes, Colan E.,Harris, Kenneth D. M.,Browne, Duncan L.
supporting information, p. 2336 - 2341 (2020/06/05)
A range of diazonium salts and their corresponding triazenes have been prepared in order to directly compare their relative thermal stabilities (via initial decomposition temperature) from differential scanning calorimetry (DSC) data. A structure-stability relationship has been explored to investigate trends in stability, depending on the aromatic substituent and the structure of the secondary amine component of the diazonium salts and triazenes. All of the triazenes investigated show significantly greater stability (many are stable above 200 °C) compared with the corresponding diazonium salts, which show varying stabilities.
Synthesis of triazenes by using aryl diazonium silica sulfates under mild conditions
Zarei, Amin,Khazdooz, Leila,Aghaei, Hamidreza,Azizi, Ghobad,Chermahini, Alireza Najafi,Hajipour, Abdol R.
, p. 295 - 302 (2013/11/19)
An efficient, fast and straightforward procedure for the synthesis of aryltriazenes is described in the present paper by using aryl diazonium silica sulfates and secondary amines. Using the present method, different kinds of aryl diazonium silica sulfates
Synthesis of Biaryls from Aryltriazenes
Patrick, Timothy B.,Willaredt, Richard P.,DeGonia, David J.
, p. 2232 - 2235 (2007/10/02)
Aryltriazenes react with aromatic solvents in the presence of trifluoroacetic acid to produce biaryls.The mechanism of the reaction involves the formation of arenediazonium trifluoroacetates which lose nitrogen to give mainly aryl radicals.
