6267-02-3

Basic information

• Product Name: 9,9-dimethylcarbazine
• Synonyms: 9,9-dimethylcarbazine;9,10-dihydro-9,9-dimethyl-acridin;Product of diphenylamine and acetone;9,9-Dimethylacridan;NSC 36671;9,9-Dimethyl-9,1-dihydroacridine;9,9-dimethyl-10H-acridine;BLE, BLE-W, BLE-C
• CAS NO: 6267-02-3
• Molecular Formula: C₁₅H₁₅N
• Molecular Weight: 209.2863
• EINECS: 228-436-9
• Mol File: 6267-02-3.mol
• Article Data: 27

Chemical Properties

• Melting Point: 120-126℃
• Boiling Point: 155°C/1mmHg(lit.)
• Flash Point: 162.3 °C
• Appearance: /
• Density: 1.043 g/cm³
• Vapor Pressure: 0.000147mmHg at 25°C
• Refractive Index: 1.577
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• PKA: 2.05±0.40(Predicted)
• CAS DataBase Reference: 9,9-dimethylcarbazine(CAS DataBase Reference)
• NIST Chemistry Reference: 9,9-dimethylcarbazine(6267-02-3)
• EPA Substance Registry System: 9,9-dimethylcarbazine(6267-02-3)

Safety Data

• Hazardous Substances Data: 6267-02-3(Hazardous Substances Data)

Usage

Chemical Properties

Dark brown viscous body

InChI:InChI=1/C15H15N/c1-15(2)11-7-3-5-9-13(11)16-14-10-6-4-8-12(14)15/h3-10,16H,1-2H3

Upstream product

• 122-39-4 diphenylamine 
• 67-64-1 acetone 
• 578-95-0 10H-acridin-9-one 
• 591-50-4 iodobenzene 
• 112817-88-6 3-methyl-1-phenyl-1H-indole 
• 108-86-1 bromobenzene 
• 38158-59-7 N-(2-isopropylphenyl)aniline 
• 62-53-3 aniline 
• 7073-69-0 2-(2-bromophenyl)propanol 
• 35708-19-1 Methyl N-phenylanthranilate 
• 75-16-1 methylmagnesium bromide 
• 91-40-7 2-(phenylamino)benzoic acid 
• 2479-47-2 4,4'-(1-methyl-ethane-1,1-diyl)-bis-aniline 
• 2980-26-9 2,2-bis-(4-anilino-phenyl)-propane 

Downstream Products

• 73183-87-6 10-(2-Benzoylphenyl)-9,10-dihydro-9,9-dimethylacridin 
• 110045-74-4 N-benzyl-9,9-dimethyl-9,10-dihydroacridine 
• 1319720-64-3 2-bromo-9,9-dimethyl-10-phenyl-9,10-dihydro-acridine 
• 1361126-03-5 N-(2-chlorophenyl)-9,9-dimethyl-10-phenyl-9,10-dihydroacridin-2-amine 
• 1361126-04-6 13,13-dimethyl-5-phenyl-11,13-dihydro-5H-indolo[2,3-b]acridine 
• 1357066-47-7 C₃₃H₂₇BN₂O₂ 
• 1357066-14-8 C₄₉H₃₆N₄ 
• 1319720-65-4 C₂₉H₂₆N₂O₂ 
• 1319720-66-5 C₃₀H₃₀N₂O 
• 1319720-67-6 C₃₀H₂₈N₂ 
• 1319720-68-7 C₃₆H₃₁BrN₂ 
• 1319720-69-8 C₃₆H₃₃BN₂O₂ 
• 1319720-63-2 C₄₆H₃₈N₄ 
• 1333316-35-0 2,7-dibromo-9,9-dimethyl-9,10-dihydroacridine 

Relevant articles and documents

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Deuterated organic compounds for organic light-emitting diode and organic light-emitting diode including the same

The present invention relates to an organic electroluminescent compound represented by chemical formula A and an organic light emitting device comprising the same. Substituents Y, Ar2 , L3 , K, p and x are as defined in the description of the invention. [Chemical A] (by machine translation)

New reductive rearrangement of: N-arylindoles triggered by the grubbs-stoltz reagent et3sih/kotbu

N-Arylindoles are transformed into dihydroacridines in a new type of rearrangement, through heating with triethylsilane and potassium tert-butoxide. Studies indicate that the pathway involves (i) the formation of indole radical anions followed by fragmentation of the indole C2-N bond, and (ii) a ring-closing reaction that follows a potassium-ion dependent hydrogen atom transfer step. Unexpected behaviors of 'radical-trap' substrates prove very helpful in framing the proposed mechanism.