62693-22-5Relevant articles and documents
Carbene-Catalyzed Formal [3+3] Cycloaddition Reaction for Access to Substituted 2-Phenylbenzothiazoles
Ni, Zhibin,Mou, Chengli,Zhu, Xun,Qi, Puying,Yang, Song,Chi, Yonggui Robin,Jin, Zhichao
supporting information, p. 492 - 495 (2020/01/24)
A carbene-catalyzed oxidative cycloaddition reaction is developed for efficient access to multi-functionalized 2-phenylbenzothiazoles. A broad scope of heavily substituted arenes bearing 2-benzothiazole groups have been prepared in good to excellent yields. The remote C(sp2)–H bond in the substituted arene products can be activated by Pd catalysts in regio-selective fashion with the direction of the 2-benzothiazole groups.