627-37-2

Basic information

• Product Name: N-Allylmethylamine
• Synonyms: 2-Propen-1-amine, N-methyl-;allylmethylamine;methylallylamine;N-Allyl-N-methylamine;n-methyl-2-propen-1-amin;n-methyl-2-propen-1-amine;n-methyl-allylamin;N-ALLYLMETHYLAMINE
• CAS NO: 627-37-2
• Molecular Formula: C₄H₉N
• Molecular Weight: 71.12
• EINECS: 210-996-0
• Mol File: 627-37-2.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 64-66 °C(lit.)
• Flash Point: −19 °F
• Appearance: colourless liquid,
• Density: 0.741 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.412(lit.)
• Storage Temp.: 2-8°C
• PKA: 9.88±0.10(Predicted)
• Water Solubility: Miscible with water.
• BRN: 1098387
• CAS DataBase Reference: N-Allylmethylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Allylmethylamine(627-37-2)
• EPA Substance Registry System: N-Allylmethylamine(627-37-2)

Safety Data

• Hazard Codes: F,T
• Statements: 11-23/24/25-34
• Safety Statements: 26-36/37/39-45-37/39
• RIDADR: UN 3286 3/PG 2
• WGK Germany: 3
• RTECS: UC6632500
• F: 9-34
• HazardClass: 3
• PackingGroup: II
• Hazardous Substances Data: 627-37-2(Hazardous Substances Data)

Usage

Description

N-Allylmethylamine is a colorless to light yellow liquid with chemical properties that make it suitable for various applications in different industries. It is a functional monomer that can be used to create a range of products, including films and photo-catalytic cells.

Uses

Used in Chemical Production:
N-Allylmethylamine is used as a key component in the production of N-allyl-α,α-dichloro-N-methylacetamide, a compound with various applications in the chemical industry.
Used in Polymer Science:
N-Allylmethylamine is used as a functional monomer for coordinating with Cd(II)/Zn(II) ions to create poly methyl methacrylate-butyl methacrylate-N-allylmethylamine (PMBA) films. These films serve as building blocks in the fabrication of photo-catalytic cells, which are essential for energy conversion and environmental applications.
Used in Environmental Applications:
The PMBA films, which incorporate N-Allylmethylamine, are useful in the development of photo-catalytic cells. These cells play a crucial role in environmental applications, such as water purification and air purification, by harnessing the power of sunlight to break down pollutants and generate clean energy.

InChI:InChI=1/C4H9N/c1-3-4-5-2/h3,5H,1,4H2,2H3

Upstream product

• 107-11-9 1-amino-2-propene 
• 74-88-4 methyl iodide 
• 179404-69-4 N-methyl-N-allyltrifluoroacetamide 
• 107-05-1 3-chloroprop-1-ene 
• 74-89-5 methylamine 
• 16250-37-6 N-allylformamide 
• 60-29-7 diethyl ether 
• 57-06-7 N-allyl isothiocyanate 
• 57041-73-3 N-allyl-N-methyl-(bisdimethylamino) phosphoramide 
• 68003-55-4 benzylidene allylamine 
• 77-78-1 dimethyl sulfate 
• 106-95-6 allyl bromide 
• 89851-56-9 3-(allyl(methyl)amino)propanenitrile 
• 1476-23-9 allylisocyanate 

Downstream Products

• 93-88-9 phenpromethamine 
• 2155-94-4 N,N-dimethyl-2-propen-1-amine 
• 92243-73-7 (allylmethylamino)-phenyl-chloroborane 
• 872-50-4 1-methyl-pyrrolidin-2-one 
• 2687-90-3 N-methyl-N-allyl-formamide 
• 20240-70-4 N-allyl-N-methylhydrazine 
• 210241-75-1 2-amino-5-chloro-N-methyl-N-(2-propenyl)benzamide 
• 403607-31-8 N-allyl-N'-methyl-3α-(3,5-dimethylbenzoyl)amino-12α-hydroxy-5β-cholan-24-amide 
• 403607-32-9 N-allyl-N'-methyl-3α-(3,5-dichlorobenzoyl)amino-12α-hydroxy-5β-cholan-24-amide 
• 403607-23-8 N-allyl-N'-methyl-3α-hydroxy-12α-(3,5-dimethylbenzoyl)amino-5β-cholan-24-amide 
• 403607-24-9 N-allyl-N'-methyl-3α-hydroxy-12α-(3,5-dichlorobenzoyl)amino-5β-cholan-24-amide 

Relevant articles and documents

Highly enantioselective intramolecular cyclopropanation reactions of N-Allylic-N-methyldiazoacetamides catalyzed by chiral dirhodium(II) carboxamidates

Catalytic diazo decomposition of representative N-allylic-N- methyldiazoacetamides produced the corresponding intramolecular cyclopropanation products in good to excellent yields and with exceptional enantiocontrol. In the simplest case, with N-allyl-N-methyldiazoacetamide, catalysis by dirhodium(II) tetrakis[methyl 2-oxapyrrolidine-5(S)-carboxylate], Rh 2(5(S)-MEPY)4, achieved the highest yield and enantioselectivity (93% ee). Dirhodium(II) tetrakis[methyl 2-oxo-1-(3- phenylpropanoyl) imidazolidin-4(S)-carboxylate], Rh2(4S)-MPPIM) 4, was preferred for substituted N-allylic-N-methyldiazoacetamides from which 92-95% ee's were obtained in intramolecular cyclopropanation reactions (88-95% yields), even when the catalyst was employed in only 0.1 mol %. Competition with intramolecular dipolar cycloaddition was minimized with the use of Nmethyldiazoacetamides relative to N-tert-butyldiazoacetamides.

Synthesis of Mixed Secondary and Tertiary Amines

Abstract: A one-stage and facile method of synthesis of expensive methyl- and ethyl(allyl)amines, methyl- and ethyl(prop-2-ynyl)amines, and methyl- and ethyl(allyl)(3-phenylprop-2-ynyl)amines is developed. The synthesized amines present practical interest, because some (prop-2-ynyl)amines are used in the therapy cancer.

Synthesis and characterization of novel carbene complexes of phosphorus(V) fluorides with potential liquid-crystalline properties

A series of novel push-push I and push-pull II carbene-stabilized complexes of phosphorus(V) fluorides bearing substituents with liquid-crystalline properties were synthesized by the oxidative addition of difluoroamines to phosphorus(III) halides. These octahedral complexes were characterized by NMR spectroscopy and X-ray analysis.

2,3-oxidosqualene-lanosterol cyclase inhibitors

The present invention relates to piperidine derivatives useful for the treatment and/or prophylaxis of diseases which are associated with 2,3-oxidosqualene-lanosterol cyclase such as hypercholesterolemia, hyperlipemia, arteriosclerosis, vascular diseases, mycoses, gallstones, tumors and/or hyperproliferative disorders, and treatment and/or prophylaxis of impaired glucose tolerance and diabetes.