627510-81-0

Basic information

• Product Name: 4-BroMo-2-phenyl-1H-pyrrolo[2,3-c]pyridine
• Synonyms: 4-BroMo-2-phenyl-1H-pyrrolo[2,3-c]pyridine
• CAS NO: 627510-81-0
• Molecular Formula: C13H9BrN2
• Molecular Weight: 273.12796
• Mol File: 627510-81-0.mol
• Article Data: 1

Chemical Properties

• Melting Point: 234-238 °C (decomp)(Solv: ethyl ether (60-29-7); hexane (110-54-3))
• Boiling Point: 457.7±40.0 °C(Predicted)
• Appearance: /
• Density: 1.546±0.06 g/cm3(Predicted)
• PKA: 13.53±0.40(Predicted)
• CAS DataBase Reference: 4-BroMo-2-phenyl-1H-pyrrolo[2,3-c]pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-BroMo-2-phenyl-1H-pyrrolo[2,3-c]pyridine(627510-81-0)
• EPA Substance Registry System: 4-BroMo-2-phenyl-1H-pyrrolo[2,3-c]pyridine(627510-81-0)

Safety Data

• Hazardous Substances Data: 627510-81-0(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 69872-15-7 3-bromo-4-methyl-5-nitropyridine 
• 627510-77-4 3-bromo-5-nitro-4-[(E)-2-phenylethenyl]pyridine 

Relevant articles and documents

Synthesis of 2-aryl-1-hydroxyazaindoles and 2-arylazaindoles via oxidation of o-hydroxyaminostyrylpyridines

2-Aryl-1-hydroxyazaindoles (pyrrolopyridin-1-ols) are prepared via an oxidation/cyclization of o-hydroxyaminostyrylpyridines with DDQ. Reduction of the N-OH bond affords the corresponding 2-arylazaindoles (1H-pyrrolopyridines). The scope of the cyclization is explored via (i) the condensation of 4-methyl-3-nitropyridine with various aryl aldehydes to afford 2-aryl substituted 6-azaindoles and, (ii) the synthesis of 2-phenyl-4-, 5- and 7-azaindoles.