6289-83-4

Basic information

• Product Name: 1,4-Cyclohexanediacetate
• Synonyms: Cyclohexanediacetate;1α,4β-Diacetoxycyclohexane;1β,4α-Cyclohexanediol diacetate;Diacetic acid 1α,4β-cyclohexylene ester;1,4-Cyclohexanedol Diacetate
• CAS NO: 6289-83-4
• Molecular Formula: C₁₀H₁₆O₄
• Molecular Weight: 198.21576
• Mol File: 6289-83-4.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 249.7°C at 760 mmHg
• Flash Point: 115.4°C
• Appearance: /
• Density: 1.09g/cm³
• Vapor Pressure: 0.0226mmHg at 25°C
• Refractive Index: 1.457
• CAS DataBase Reference: 1,4-Cyclohexanediacetate(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Cyclohexanediacetate(6289-83-4)
• EPA Substance Registry System: 1,4-Cyclohexanediacetate(6289-83-4)

Safety Data

• Hazardous Substances Data: 6289-83-4(Hazardous Substances Data)

Usage

Structure

Diester formed from the condensation of two molecules of acetic acid with one molecule of 1,4-cyclohexanediol

Physical state

Colorless, odorless, and viscous liquid

Uses

a. Plasticizer in the production of various plastic and rubber products
b. Manufacturing of coatings, adhesives, and sealants
c. Solvent in the pharmaceutical and chemical industries
d. Fragrance ingredient in the production of perfumes and personal care products

Scent

Pleasant and mild scent

Appearance

Colorless liquid

Odor

Odorless

Viscosity

Viscous

Chemical properties

a. Ester formation through condensation reaction with acetic acid and 1,4-cyclohexanediol
b. Solvent properties for pharmaceutical and chemical applications

Industrial applications

Widely used in the production of various consumer goods, including plastics, rubber, coatings, adhesives, sealants, perfumes, and personal care products.

InChI:InChI=1/C10H16O4/c1-7(11)13-9-3-5-10(6-4-9)14-8(2)12/h9-10H,3-6H2,1-2H3

Upstream product

• 556-48-9 1,4-Cyclohexanediol 
• 75-36-5 acetyl chloride 
• 108-24-7 acetic anhydride 
• 279-49-2 7-oxabicyclo(2.2.1)heptane 
• 64-17-5 ethanol 
• 26785-22-8 trans-1,4-bis-(toluene-sulfonyl-⁽⁴⁾-oxy)-cyclohexane 
• 127-08-2 potassium acetate 
• 931-71-5 cis-1,4-cyclohexanediol 
• 64-19-7 acetic acid 
• 123-31-9 hydroquinone 
• 100314-09-8 trans-N_.N'-Dinitroso-N_.N'-dicarbethoxy-1.4-diamino-cyclohexan 
• 592-42-7 1,5-Hexadien 
• 1600-27-7 mercury(II) diacetate 
• 6995-79-5 cyclohexane-1,4-diol 

Downstream Products

• 69558-44-7 trans-4-acetoxy-1-cyclohexanol 
• 16890-91-8 trans-1,4-dichlorocyclohexane 
• 13618-83-2 trans-1,4-dibromocyclohexane 
• 931-71-5 cis-1,4-cyclohexanediol 
• 6995-79-5 cyclohexane-1,4-diol 

Relevant articles and documents

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Meerwein-Ponndorf-Verley-type reductive acetylation of carbonyl compounds to acetates by lanthanide complexes in the presence of isopropenyl acetate

Meerwein-Ponndorf-Verley-type reductive acetylation of carbonyl compounds to acetates was successfully carried out in the presence of isopropenyl acetate under the influence of a catalytic amount of Ln(O(i)Pr)3 at room temperature. Various carbonyl compounds were converted into the corresponding acetates in fair to good yields. (C) 2000 Elsevier Science Ltd.

STEREOSTRUCTURE OF RENGYOL AND ISORENGYOL, PHENYLETHANOIDS OF FORSYTHIA SUSPENSA

Determination of the stereostructure of rengyol (1), a novel nonaromatic phenylethanoid natural product isolated from Forsythia suspensa, by synthetic means has been described.The Reformatsky reaction of 4-acetoxycyclohexanone with ethyl bromoacetate afforded two isomeric acetoxy esters (5, 6) and the one (5) which has an equatorial acetoxyl group yielded on LAH reduction a triol identified as rengyol (1).The isomer (7), obtained similarly from the other isomeric acetoxy ester (6), has also been isolated from the natural source and is named isorengyol.Further, dehydratation of the esters (5, 6) and subsequent pyrolytic deacetoxylation afforded a 1,3-cyclohaxadiene derivative (12), which on photosensitized cis-dioxygenation, followed by reduction, yielded rengyol (1) establishing its stereostructure to have 1,4-cis-cyclohexanediol system.These results supported the previous conclusion based on the 1H and 13C NMR spectral data.