6292-95-1Relevant articles and documents
Hermans,Streef
, p. 133,142 (1964)
Scaleable two-component gelator from phthalic acid derivatives and primary alkyl amines: Acid-base interaction in the cooperative assembly
Su, Ting,Hong, Kwon Ho,Zhang, Wannian,Li, Fei,Li, Qiang,Yu, Fang,Luo, Genxiang,Gao, Honghe,He, Yu-Peng
, p. 4066 - 4073 (2017/07/10)
A series of phthalic acid derivatives (P) with a carbon-chain tail was designed and synthesized as single-component gelators. A combination of the single-component gelator P and a non-gelling additive n-alkylamine A through acid-base interaction brought about a series of novel phase-selective two-component gelators PA. The gelation capabilities of P and PA, and the structural, morphological, thermo-dynamic and rheological properties of the corresponding gels were investigated. A molecular dynamics simulation showed that the H-bonding network in PA formed between the NH of A and the carbonyl oxygen of P altered the assembly process of gelator P. Crude PA could be synthesized through a one-step process without any purification and could selectively gel the oil phase without a typical heating-cooling process. Moreover, such a crude PA and its gelation process could be amplified to the kilogram scale with high efficiency, which offers a practical economically viable solution to marine oil-spill recovery.