62931-81-1

Basic information

• Product Name: Pt3(μCO)3(P-tert.-Bu2Ph)3
• Synonyms: Pt3(μCO)3(P-tert.-Bu2Ph)3
• CAS NO: 62931-81-1
• Molecular Weight: 1336.2
• Mol File: 62931-81-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Pt3(μCO)3(P-tert.-Bu2Ph)3(CAS DataBase Reference)
• NIST Chemistry Reference: Pt3(μCO)3(P-tert.-Bu2Ph)3(62931-81-1)
• EPA Substance Registry System: Pt3(μCO)3(P-tert.-Bu2Ph)3(62931-81-1)

Safety Data

• Hazardous Substances Data: 62931-81-1(Hazardous Substances Data)

Upstream product

• 97703-27-0 Pt2(μ-SO2)(CO)2(P-tert.-Bu2Ph)2 
• 1184-78-7 trimethylamine-N-oxide 
• 106763-09-1 Pt₂Cl₂(CO)2(P(C(CH₃)3)2C₆H₅)2 
• 106763-08-0 PtHCl(CO)(P(C(CH₃)3)2C₆H₅) 
• 16940-66-2 sodium tetrahydroborate 
• 106819-57-2 PtHCl(CO)(P(C(CH₃)3)2C₆H₅) 
• 32673-25-9 di(tertbutyl)phenylphosphine 

Downstream Products

• 118714-49-1 Pt₂I₂(CO)2(P-tert.-Bu₂Ph₂)2 
• 97719-79-4 Pt3(μ-SO2)(μ-CO)(P-tert.-Bu2Ph)3 
• 97703-27-0 Pt2(μ-SO2)(CO)2(P-tert.-Bu2Ph)2 
• 97703-28-1 Pt₃(CO)(P(C(CH₃)3)2C₆H₅)3(SO₂)2 
• 97689-48-0 Pt(μ-S)(CO)2(P tert.-Bu2Ph)2 
• 106763-08-0 PtHCl(CO)(P(C(CH₃)3)2C₆H₅) 
• 106819-57-2 PtHCl(CO)(P(C(CH₃)3)2C₆H₅) 
• 97689-47-9 Pt₂(P(C(CH₃)3)2C₆H₅)2(CO)2(CS₂)2 
• 91686-59-8 Pt₂(CS₂)2(P(C(CH₃)3)2C₆H₅)2 
• 97689-49-1 Pt₃(CO)3(P(C(CH₃)3)2C₆H₅)2(P(C₆H₁₁)3) 
• 71080-85-8 Pt₃(CO)3(P(C(CH₃)3)(C₆H₅)2)3 
• 62922-35-4 trans-bis(di-t-butylphenylphosphine)chlorohydrogenoplatinum(II) 
• 101246-99-5 PtCl₂(CO)(P(C(CH₃)3)2C₆H₅) 
• 106763-09-1 Pt₂Cl₂(CO)2(P(C(CH₃)3)2C₆H₅)2 

Relevant articles and documents

Reactivity of the "Pt2(μ2-S)" unit in dimeric platinum complexes

Reaction of the complex Pt3(μ-CO)3(PtBu2Ph)3 (1) with an atmosphere of hydrogen sulfide or a stoichiometric quantity of elemental sulfur results in the formation of Pt2(M-S)(CO)2

Reactivity and ligand exchange in triplatinum clusters

The phosphine ligands, L, in the triplatinum clusters Pt3(CO)3L3 have been found to undergo a facile ligand substitution reaction with 3 equiv of L′ to give Pt3(CO)3L′3 where L = P-t-Bu3 and L′ = P-t-Bu2Ph, L = P-t-Bu2Ph and L′ = P-t-BuPh2, PCy3, and P-i-Pr3, and L = PCy3 and L′ = P-i-Pr3. The substitution occurs by an associative mechanism with the Pt3 triangle remaining intact during the process. Mixtures of Pt3(CO)3(P-t-Bu2Ph)3, 1, and either Pt3(13CO)3(P-t-Bu2Ph)3 or Pt3(CO)3(PCy3)3, 2, scramble both phosphine and carbonyl ligands in a much slower reaction (approximately 1 h at 25 °C whereas L′ substitution occurs in about 25 s). Reactions of the cluster 1 with CS2, OCS, and SO2 also have been examined. In all cases, fragmentation of the trimer occurs to give dimeric products. The reaction of 1 and CS2 results in formation of either Pt2(μ-CS2)2(P-t-Bu2Ph) 2, or Pt2(μ-S)(CO)2(P-t-Bu2Ph)2, 4, depending on reaction conditions, whereas 4 is obtained from the reaction of 1 with OCS. Treatment of 1 with SO2 at 25 °C gives Pt2(μ-SO2)-(CO)2(P-t-Bu2Ph) 2, 5, which on prolonged standing in solution at 25 °C converts to the triplatinum cluster Pt3(CO)2(SO2) (P-t-Bu2>Ph)3, 6. 31P NMR spectroscopy reveals that the initial reaction gives mixtures of 5, 6, and Pt3(SO2)2(CO)(P-t-Bu2Ph) 3.