6301-53-7

Basic information

• Product Name: 3-(4-phenylphenyl)cyclohex-2-en-1-one
• Synonyms: 3-(4-phenylphenyl)cyclohex-2-en-1-one
• CAS NO: 6301-53-7
• Molecular Formula: C₁₈H₁₆O
• Molecular Weight: 248.32
• Mol File: 6301-53-7.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 399°C at 760 mmHg
• Flash Point: 175.5°C
• Appearance: /
• Density: 1.11g/cm³
• Vapor Pressure: 1.41E-06mmHg at 25°C
• Refractive Index: 1.599
• CAS DataBase Reference: 3-(4-phenylphenyl)cyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-phenylphenyl)cyclohex-2-en-1-one(6301-53-7)
• EPA Substance Registry System: 3-(4-phenylphenyl)cyclohex-2-en-1-one(6301-53-7)

Safety Data

• Hazardous Substances Data: 6301-53-7(Hazardous Substances Data)

Usage

InChI:InChI=1/C18H16O/c19-18-8-4-7-17(13-18)16-11-9-15(10-12-16)14-5-2-1-3-6-14/h1-3,5-6,9-13H,4,7-8H2

Upstream product

• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 930-68-7 cyclohexenone 
• 5467-74-3 4-Bromophenylboronic acid 
• 98-80-6 phenylboronic acid 
• 5122-99-6 4-iodophenylboronic acid 
• 1679-18-1 4-Chlorophenylboronic acid 
• 5122-94-1 4-biphenylboronic acid 
• 10468-72-1 1-([1,1'-biphenyl]-4-yl)cyclohexan-1-ol 
• 15321-51-4 diiron nonacarbonyl 

Downstream Products

• 625445-10-5 3-biphenyl-4-yl-cyclohex-2-enol 
• 66924-54-7 3-Biphenyl-4-yl-4'-biphenyl-3-yl-biphenyl 
• 14739-51-6 [1,1';4',1'';3'',1''';4''',1'''';4'''',1''''']Sexiphenyl 
• 5660-38-8 [1,1';2',1'';3'',1''';4''',1'''']Quinquephenyl 

Relevant articles and documents

Fe2(CO)9-mediated [5+1] cycloaddition of vinylcyclopropanes and CO for the synthesis of α, β-cyclohexenones

A Fe2(CO)9-mediated [5+1] cycloaddition of vinylcyclopropanes (VCPs) and CO to α, β-cyclohexenones has been developed. The reaction can tolerate aryl and aliphatic groups at the α-position of VCPs, while VCP substrates with vinyl or alkynyl substitutions are not suitable ones. In addition, this reaction can also be used to synthesize bicyclic rings if an aryl group is attached to the vinyl moiety of the substrate. Compared to the Fe(CO)5-mediated [5+1] reaction, the use of cheap and safe Fe2(CO)9 and abandoning the photo-irradiation conditions are the two major advantages of the present method.

Aerobic oxidative heck/dehydrogenation reactions of cyclohexenones: Efficient access to meta-substituted phenols

Jockeying for the (meta)position: A new dicationic palladium(II) catalyst, employing a 6,6′-dimethyl-2,2′-bipyridine ligand, promotes both the aerobic oxidative Heck coupling and dehydrogenation reactions of cyclohexenones. These reactions may be combined in a one-pot sequence to enable the straightforward synthesis of meta-substituted phenols (see scheme). Copyright