63105-98-6Relevant articles and documents
Photochemistry with fast sample renewal using cluster beams: Formation of rare-gas halides in charge-transfer reactions in NF3-doped rare-gas clusters
Moussavizadeh,Von Haeften,Museur,Kanaev,Castex,Von Pietrowski,Moeller
, p. 327 - 333 (1999)
Charge transfer reactions in free clusters are observed in a photoluminescence study on doped rare-gas clusters (Rg clusters, Rg = Ar, Kr and Xe). Following photoexcitation into the first absorption bands of Rg clusters, fluorescence from free RgF* excimers ejected from the clusters and from Rg2F* excimers localized in the interior of the clusters is observed. The results show that the reaction dynamics in clusters differs considerably from that in the gas and solid phase.