63113-40-6

Basic information

• Product Name: [1,1'-Biphenyl]-4-amine, N,N,2-trimethyl-
• CAS NO: 63113-40-6
• Molecular Formula: C15H17N
• Molecular Weight: 211.307
• Mol File: 63113-40-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1,1'-Biphenyl]-4-amine, N,N,2-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1'-Biphenyl]-4-amine, N,N,2-trimethyl-(63113-40-6)
• EPA Substance Registry System: [1,1'-Biphenyl]-4-amine, N,N,2-trimethyl-(63113-40-6)

Safety Data

• Hazardous Substances Data: 63113-40-6(Hazardous Substances Data)

Upstream product

• 825-85-4 N,N-dimethyl-p-toluidine N-oxide 
• 71-43-2 benzene 

Relevant articles and documents

Acid-Catalyzed Reactions of N-Arylhydroxylamines and Related Compounds with Benzene. Iminium-Benzenium Ions

N-Arylhydroxylamines react with benzene in the presence of trifluoroacetic acid (TFA) at room temperature to give diphenylamines.When TFA was replaced by a strong acid, trifluoromethanesulfonic acid (TFSA), the major products were aminobiphenyls.The nature of the reaction was explored by reactions of 4-substituted phenylhydroxylamines and dialkylaniline N-oxides with benzene.Thus, it was demonstrated that the reactive intermediates are onium-benzenium dications which are trapped by benzene to give aminobiphenyls by a mechanism similar to the Friedel-Krafts alkylation.Further evidence for the proposed reaction mechanism was the observation that nitrosobenzene and azoxybenzene reacted with benzene to give analogous products in the presence of the stronger acid.