63131-36-2

Basic information

• Product Name: ethyl 3-(4-chlorophenyl)-2-methyl-3-oxopropanoate
• Synonyms: ethyl 3-(4-chlorophenyl)-2-methyl-3-oxopropanoate
• CAS NO: 63131-36-2
• Molecular Weight: 240.686
• Mol File: 63131-36-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: ethyl 3-(4-chlorophenyl)-2-methyl-3-oxopropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 3-(4-chlorophenyl)-2-methyl-3-oxopropanoate(63131-36-2)
• EPA Substance Registry System: ethyl 3-(4-chlorophenyl)-2-methyl-3-oxopropanoate(63131-36-2)

Safety Data

• Hazardous Substances Data: 63131-36-2(Hazardous Substances Data)

Upstream product

• 2881-63-2 ethyl (4-chlorobenzoyl)acetate 
• 544-97-8 dimethyl zinc(II) 
• 99-91-2 para-chloroacetophenone 
• 105-58-8 Diethyl carbonate 
• 74-88-4 methyl iodide 

Downstream Products

• 1373511-26-2 ethyl 2-(4-chlorobenzoyl)-1-tosylaziridine-2-carboxylate 
• 139400-78-5 6-(4-chloro-phenyl)-5-methyl-pyrimidine-2,4-diyldiamine 
• 182633-14-3 3-(4-Chlorophenyl)-4-methyl-1-phenyl-4,5-dihydropyrazol-5-one 
• 4865-05-8 2-amino-6-(4-chloro-phenyl)-5-methyl-3H-pyrimidin-4-one 
• 681178-99-4 ethyl 1-(2-chlorophenyl)-5-(4-chlorophenyl)-4-methyl-1 H-pyrazole-3-carboxylate 

Relevant articles and documents

Complementing Pyridine-2,6-bis(oxazoline) with Cyclometalated N-Heterocyclic Carbene for Asymmetric Ruthenium Catalysis

A strategy for expanding the utility of chiral pyridine-2,6-bis(oxazoline) (pybox) ligands for asymmetric transition metal catalysis is introduced by adding a bidentate ligand to modulate the electronic properties and asymmetric induction. Specifically, a ruthenium(II) pybox fragment is combined with a cyclometalated N-heterocyclic carbene (NHC) ligand to generate catalysts for enantioselective transition metal nitrenoid chemistry, including ring contraction to chiral 2H-azirines (up to 97 % ee with 2000 TON) and enantioselective C(sp3)?H aminations (up to 97 % ee with 50 TON).

A copper-mediated oxidative coupling route to 3H- and 1H-indoles from N-aryl-enamines

A facile copper(II)-mediated C-H bond oxidation and C-C bond formation procedure has been applied to the synthesis of indole derivatives. Intramolecular oxidative coupling of 3,3-disubstituted enamines proceeded using a non-expensive and air-stable copper