633-68-1Relevant articles and documents
New blue emitting material with asymmetric limb structure
Hahn, Seung-Hoon,Lee, Jonghee,Chu, Hye Yong,Lee, Jeong-Ik,Lee, Yun Ji,Hwang, Jaeyoung,Shin, Sung Chul,Kim, Yun-Hi
, p. 355 - 359 (2015)
The new assymmetric limb-structured blue light emitting material, composed of anthracene main core, naphthalene units at 9, 10-position of anthracene and xylene units at 2,3-positon of anthracene, was designed and synthesized. The three-dimensional structure from theoretical calculation was characterized to elucidate non-copolar structure with inhibited intermolecular interaction. The limb-structured blue material was thermally stable up to 373°C with Tg of 143°C. ITO/TAPC/CBP (3% BMPNA)/Bphen/LiF/Al device exhibits the maximum quantum efficiency of 3.42% and maximum current efficiency of 3.07 cd/A with deep blue emission of (0.141, 0.115) CIE coordinates.
New limb structured blue light emitting materials for OLEDs
Kim, Ran,Yoo, Seung-Jin,Kim, Eun-Kyung,Yu, Han Sung,Shin, Sung Chul,Lee, Sang-Kyung,Kwon, Soon-Ki,Kim, Yun-Hi
, p. 384 - 391 (2012)
We designed new three limb structured anthracene derivatives, PNA, NNA and FNA, which are composed of an anthracene core and naphthalene units at the 9,10-positions of anthracene and phenyl, naphthalene and fluorene units at the 2,3-positons of anthracene. The effect of the introduced limbs on the 2,3,9,10-positions of anthracene was studied. The doped EL devices using ADN as a host and (3% PNA or NNA or FNA) as a dopant showed similar maximum quantum efficiency of 3.9%-4.3% with high color purity of (0.15, 0.13).
Synthesis and photophysical properties of dinaphtho[2,3-b:2′,3′-i]dihydrophenazine derivatives
Iwanaga, Tetsuo,Asano, Naoto,Yamada, Haruo,Toyota, Shinji
supporting information, p. 1113 - 1116 (2019/03/23)
A dinaphtho[2,3-b:2′,3′-i]dihydrophenazine (DNP) derivative was synthesized by Buchwald-Hartwig cross-coupling, and its electronic spectrum was compared with that of dinaphtho[b,i]dihydrophenazine-5,18-dione (DNP-dione) as an anthraquinone analog. An absorption band of DNP is attributed to extension of π-conjugation over the entire molecule via the N atom. DNP-dione showed a broad absorption band in the range 450–490 nm due to intramolecular charge-transfer interactions. Additionally, the absolute fluorescence quantum yield of DNP was larger than that of DNP-dione. DNP-dione exhibited reversible oxidation peaks and a similar oxidation potential to DNP, since there are very weak electronic interactions between the anthracene and anthraquinone units across the N atoms with the 4-octyloxyphenyl substituent.