635678-43-2

Basic information

• Product Name: (1R,2S,5R)-2-(1-methyl-1-phenylethyl)-5-methylcyclohexyl-(2,3-dibromo)propionate
• Synonyms: (1R,2S,5R)-2-(1-methyl-1-phenylethyl)-5-methylcyclohexyl-(2,3-dibromo)propionate
• CAS NO: 635678-43-2
• Molecular Weight: 446.222
• Mol File: 635678-43-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R,2S,5R)-2-(1-methyl-1-phenylethyl)-5-methylcyclohexyl-(2,3-dibromo)propionate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,5R)-2-(1-methyl-1-phenylethyl)-5-methylcyclohexyl-(2,3-dibromo)propionate(635678-43-2)
• EPA Substance Registry System: (1R,2S,5R)-2-(1-methyl-1-phenylethyl)-5-methylcyclohexyl-(2,3-dibromo)propionate(635678-43-2)

Safety Data

• Hazardous Substances Data: 635678-43-2(Hazardous Substances Data)

Upstream product

• 65253-04-5 (-)-8-phenylmenthol 
• 72526-00-2 (-)-8-phenylmenthyl acrylate 

Downstream Products

• 600734-37-0 (1R,2S,5R)-2-(1-methyl-1-phenylethyl)-5-methylcyclohexyl 2H-azirine-3-carboxylate 

Relevant articles and documents

Investigation of Lewis Acid-Catalyzed Asymmetric Aza-Diels-Alder Reactions of 2H-Azirines

Asymmetric Diels-Alder reactions with 2H-azirines as dienophiles have been studied. Diastereoselective reactions with an enantiopure azirine 1b, bearing a chiral auxiliary, gave substituted bi- and tricyclic tetrahydropyridines in high yield and stereoselectivity, under the influence of a Lewis acid. The novel enantioselective [4+2] cycloaddition reaction of 3-benzyl-2H-azirine carboxylate with cyclopentadiene was investigated with various chiral Lewis acid complexes and provided the corresponding tetrahydropyridines in moderate to low yield and enantioselectivity.