63591-88-8

Basic information

• Product Name: 1H-Isoindole-1,3(2H)-dione, 2-[(3-chlorobenzoyl)oxy]-
• CAS NO: 63591-88-8
• Molecular Formula: C15H8ClNO4
• Molecular Weight: 301.686
• Mol File: 63591-88-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1H-Isoindole-1,3(2H)-dione, 2-[(3-chlorobenzoyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Isoindole-1,3(2H)-dione, 2-[(3-chlorobenzoyl)oxy]-(63591-88-8)
• EPA Substance Registry System: 1H-Isoindole-1,3(2H)-dione, 2-[(3-chlorobenzoyl)oxy]-(63591-88-8)

Safety Data

• Hazardous Substances Data: 63591-88-8(Hazardous Substances Data)

Upstream product

• 524-38-9 N-hydroxyphthalimide 
• 587-04-2 m-Chlorobenzaldehyde 
• 535-80-8 3-chlorobenzoate 

Downstream Products

• 635305-47-4 2-(3-chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Relevant articles and documents

Metal-free intermolecular C-O cross-coupling reactions: Synthesis of: N -hydroxyimide esters

Selectfluor-mediated intermolecular C-O cross coupling reaction for the synthesis of N-hydroxyimide esters was developed for the first time. The reaction is applicable to the coupling of readily available aryl and alkyl aldehydes with N-hydroxyphthalimide (NHPI) and N-hydroxysuccinimide (NHSI). The resulting active esters can be directly converted into amides in one pot.

Organocatalytic amidation and esterification of aldehydes with activating reagents by a cross-coupling strategy

Formation on demand: An organocatalytic cross-coupling reaction of aldehydes with N-hydroxyimides, hexafluoroisopropyl alcohol, and sulfonimides has been developed. The resulting active intermediates can be directly converted into amides or esters in one pot. This simple method makes use of readily available starting materials, and the newly discovered activating reagents should find broad application in the synthesis of amides and esters. Copyright