63601-60-5

Basic information

• Product Name: [Ag(triphenylphosphine)2(methanesulfonate)]
• CAS NO: 63601-60-5
• Molecular Weight: 727.549
• Mol File: 63601-60-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ag(triphenylphosphine)2(methanesulfonate)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ag(triphenylphosphine)2(methanesulfonate)](63601-60-5)
• EPA Substance Registry System: [Ag(triphenylphosphine)2(methanesulfonate)](63601-60-5)

Safety Data

• Hazardous Substances Data: 63601-60-5(Hazardous Substances Data)

Upstream product

• 2386-52-9 silver methanesulfonate 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

Synthesis and characterization of organophosphine/phosphite stabilized silver(I) methanesulfonates: Crystal structures of [Ph3PAgO3SCH3] and [(Ph3P)2AgO3SCH3]

Six organophosphine/phosphite stabilized silver(I) methanesulfonates of type [LnAgO3SCH3] (L = Ph3P, n = 1, 2a; n = 2, 2b; n = 3, 2c; L = (EtO)3P; n = 1, 2d; n = 2, 2e; n = 3, 2f) were synthesized by the reaction of silver methanesulfonates with triphenylphosphine or triethylphosphite in dichloromethane under nitrogen atmosphere. These complexes were obtained in high yields and characterized by elemental analysis, 1H-, 13C{H} NMR, IR spectroscopy and thermogravimetric analysis (TGA), respectively. X-ray single crystal analysis reveals that complex 2a is a tetramer [Ph3PAgO3SCH3]4 and complex 2b is a monomer. The thermal stability of 2a has been studied by applying thermogravimetric analysis. It starts to decompose between 50 and 440 °C in a three-step process. The final residue (Ag) is about 20.50%.