63686-25-9

Basic information

• Product Name: Iridium(1+), carbonylchloro(2-diazenyl-3-nitrophenyl)bis(triphenylphosphine)-, tetrafluoroborate(1-)
• CAS NO: 63686-25-9
• Molecular Formula: C43H34ClIrN3O3P2.BF4
• Molecular Weight: 1017.19
• Mol File: 63686-25-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Iridium(1+), carbonylchloro(2-diazenyl-3-nitrophenyl)bis(triphenylphosphine)-, tetrafluoroborate(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: Iridium(1+), carbonylchloro(2-diazenyl-3-nitrophenyl)bis(triphenylphosphine)-, tetrafluoroborate(1-)(63686-25-9)
• EPA Substance Registry System: Iridium(1+), carbonylchloro(2-diazenyl-3-nitrophenyl)bis(triphenylphosphine)-, tetrafluoroborate(1-)(63686-25-9)

Safety Data

• Hazardous Substances Data: 63686-25-9(Hazardous Substances Data)

Upstream product

• 59246-46-7 bis(triphenylphosphine)carbonyliridium(I) chloride 
• 365-33-3 2-nitrobenzenediazonium tetrafluoroborate 
• 67-63-0 isopropyl alcohol 

Downstream Products

• 63686-11-3 [Ir(CO)Cl(NNC₆H₃NO₂-o)(PPh₃)2] 
• 63686-01-1 [Ir(CO)Cl(NH₂NHC₆H₃NH₂-o)(PPh₃)2]BF₄ 

Relevant articles and documents

ARYLDIAZENIDO, ARYLDIAZENE, AND ARYLHYDRAZIDO COMPLEXES. FURTHER STUDIES OF ortho-METALATED IRIDIUM COMPLEXES DERIVED FROM REACTIONS OF ARYLDIAZONIUM IONS WITH IrH(CO)(PPh3)3 AND IrH(CO)2(PPh3)2

The syntheses are described of ortho-metalated iridium arylhydrazido complexes BF4, where X=H, 4-F, 3-F, 2-F, 4-OMe, 2-OMe, 2-NO2, 3-NO2, 3-CH3, 4-CH3 and 2-CF3 from the reactions of the corresponding arenediazonium tetrafluorobo